Silane, bis([1,1'-biphenyl]-4-yl)diphenyl-

Base Information

• Chemical Name: Silane, bis([1,1'-biphenyl]-4-yl)diphenyl-
• CAS No.: 3172-33-6
• Molecular Formula: C36H28 Si
• Molecular Weight: 488.704
• Hs Code.: 2931900090
• European Community (EC) Number: 221-636-7
• NSC Number: 33025
• UNII: R4H00JMI65
• DSSTox Substance ID: DTXSID6062886
• Nikkaji Number: J217.325E
• Wikidata: Q81990327
• Mol file: 3172-33-6.mol

Synonyms:3172-33-6;Bis(p-biphenyl)diphenylsilane;Silane, bis([1,1'-biphenyl]-4-yl)diphenyl-;diphenyl-bis(4-phenylphenyl)silane;Silane, bis(4-biphenylyl)diphenyl-;Di([1,1'-biphenyl]-4-yl)diphenylsilane;R4H00JMI65;Silane, bis((1,1'-biphenyl)-4-yl)diphenyl-;1,1'-Biphenyl, 4,4''-(diphenylsilylene)bis-;EINECS 221-636-7;NSC 33025;NSC-33025;4,4''-(Diphenylsilylene)bis(1,1'-biphenyl);Bis((1,1'-biphenyl)-4-yl)diphenylsilane;Bis([1,1'-biphenyl]-4-yl)diphenylsilane;NSC33025;UNII-R4H00JMI65;C36H28Si;C36-H28-Si;DTXSID6062886;bis-(biphenyl-4-yl)-diphenyl-silane;AKOS024433056;BIS(4-BIPHENYLYL)DIPHENYLSILANE;Bis(1,1'-biphenyl-4-yl)diphenylsilane

Chemical Property of Silane, bis([1,1'-biphenyl]-4-yl)diphenyl-

Chemical Property:

• Melting Point: 169-170 °C(Solv: benzene (71-43-2); ethanol (64-17-5))
• Boiling Point: 602.9°Cat760mmHg
• Flash Point: 306°C
• PSA: 0.00000
• Density: 1.15g/cm³
• LogP: 6.39800
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 488.196027428
• Heavy Atom Count: 37
• Complexity: 586

Purity/Quality:

99% ^*data from raw suppliers

BIS(4-BIPHENYLYL)DIPHENYLSILANE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC=C(C=C2)[Si](C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=C(C=C5)C6=CC=CC=C6

Technology Process of Silane, bis([1,1'-biphenyl]-4-yl)diphenyl-

There total 3 articles about Silane, bis([1,1'-biphenyl]-4-yl)diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-bromo-1,1'-biphenyl (92-66-0) + diphenylsilyl dichloride (80-10-4) → bis-biphenyl-4-yl-diphenyl-silane (3172-33-6)

Guidance literature:

With sodium;

DOI:10.1021/ja01628a051

Reference yield:

4-biphenyllithium (1201-71-4) + diphenylsilyl dichloride (80-10-4) → bis-biphenyl-4-yl-diphenyl-silane (3172-33-6)

Guidance literature:

DOI:10.1021/jo01092a619

Reference yield:

diphenylsilyl dichloride (80-10-4) + 4'-biphenyl chloride (2051-62-9,80333-62-6) → bis-biphenyl-4-yl-diphenyl-silane (3172-33-6)

Guidance literature:

With sodium;

upstream raw materials:

4-bromo-1,1'-biphenyl

diphenylsilyl dichloride

4-biphenyllithium

4'-biphenyl chloride