4'-Methoxy[1,1'-biphenyl]-2,5-diol

Base Information

• Chemical Name: 4'-Methoxy[1,1'-biphenyl]-2,5-diol
• CAS No.: 59007-04-4
• Molecular Formula: C13H12 O3
• Molecular Weight: 216.236
• European Community (EC) Number: 261-554-9
• UNII: GP8KZ9U67C
• DSSTox Substance ID: DTXSID80207772
• Nikkaji Number: J308.589I
• Mol file: 59007-04-4.mol

Synonyms:59007-04-4;4'-methoxy[1,1'-biphenyl]-2,5-diol;4'-Methoxy(1,1'-biphenyl)-2,5-diol;EINECS 261-554-9;2-(4-methoxyphenyl)benzene-1,4-diol;GP8KZ9U67C;(p-Methoxyphenyl)hydroquinone;(4-Methoxyphenyl)hydroquinone;4'-methoxybiphenyl-2,5-diol;2-(p-Methoxyphenyl)hydroquinone;SCHEMBL11078733;2-(4-Methoxyphenyl)hydroquinone;DTXSID80207772;2-(4-Methoxyphenyl)-1,4-benzenediol;2-(4-Methoxyphenyl)-1,4-dihydroxybenzene;[1,1'-Biphenyl]-2,5-diol, 4'-methoxy-

Chemical Property of 4'-Methoxy[1,1'-biphenyl]-2,5-diol

Chemical Property:

• Boiling Point: 415.6oC at 760 mmHg
• Flash Point: 205.2oC
• PSA: 49.69000
• Density: 1.231g/cm3
• LogP: 2.77340
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 216.078644241
• Heavy Atom Count: 16
• Complexity: 211

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)C2=C(C=CC(=C2)O)O
• Uses: (4-Methoxy Phenyl) Hydroquinone is used in the synthetic preparation of side-chain-type sulfonated poly(arylene ether ketone) with pendant sulfoalkyl groups for use as electrolyte in direct methanol fuel cells.

Technology Process of 4'-Methoxy[1,1'-biphenyl]-2,5-diol

There total 12 articles about 4'-Methoxy[1,1'-biphenyl]-2,5-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

4-methoxy-aniline (104-94-9) → p-anisyl-p-benzoquinone (30100-35-7) + 2-(4-methoxyphenyl)-1,4-hydroquinone (59007-04-4)

Guidance literature:

With p-benzoquinone;

Reference yield: 62.0%

p-anisyl-p-benzoquinone (30100-35-7) → 2-(4-methoxyphenyl)-1,4-hydroquinone (59007-04-4)

Guidance literature:

With hydrogenchloride; zinc;

DOI:10.1016/j.polymer.2011.12.021

Reference yield: 53.0%

2-(4-methoxy-phenyl)-cyclohexane-1,4-dione (479075-37-1) → 2-(4-methoxyphenyl)-1,4-hydroquinone (59007-04-4) + 2-(4-methoxy-phenyl)-cyclohex-2-ene-1,4-dione

Guidance literature:

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In benzene; at 80 ℃; for 30h;

DOI:10.1016/S0040-4039(02)00163-6

upstream raw materials:

p-anisyl-p-benzoquinone

N-phenylbenzohydrazonoyl chloride

2-(4-methoxy-phenyl)-cyclohexane-1,4-dione

2-bromomethyl-2-(4-methoxy-phenyl)-cyclopentane-1,3-dione

Downstream raw materials:

2,2-dimethyl-n-valeric acid

Refernces

• 1、 Fürst, Michael C. D.,Gans, Eva,B?ck, Michael J.,Heinrich, Markus R.. "Visible-Light-Induced, Catalyst-Free Radical Arylations of Arenes and Heteroarenes with Aryldiazonium Salts". supporting information. p. 15312 - 15315. Retrieved 2017/10/20.
• 2、 Kawafuchi, Hiroyuki,Inokuchi, Tsutomu. "Novel access to cyclohexane-1,4-diones and 1,4-hydroquinones via radical 1,2-acyl rearrangement on 2-(halomethyl)cyclopentane-1,3-diones using cobaloxime-mediated electroreduction or tributyltin hydride". . p. 2051 - 2054. Retrieved 2007/10/03.