Technology Process of Benzene, 1-[1,2-bis(2-propenyloxy)ethyl]-4,5-dimethoxy-2-nitro-
There total 3 articles about Benzene, 1-[1,2-bis(2-propenyloxy)ethyl]-4,5-dimethoxy-2-nitro- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1: sodium hexamethylsilazide / 1.) THF, 0 deg C, 1 h, 2.) RT, 18 h
2: 90 percent / OsO4, 4-methylmorpholine N-oxide / 2-methyl-propan-2-ol; H2O / 45 h / Ambient temperature
3: 1.) n-butyltin oxide, 2.) tetra n-butylammonium iodide, 3.) NaH / 1.) MeOH, reflux, 2 h, 2.) toluene, reflux, 22 h, 3.) DME, RT, 1 h
With
osmium(VIII) oxide; sodium hexamethyldisilazane; tetra-(n-butyl)ammonium iodide; monobutyltin oxide; sodium hydride; 4-methylmorpholine N-oxide;
In
water; tert-butyl alcohol;
DOI:10.1021/jo00244a022
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 90 percent / OsO4, 4-methylmorpholine N-oxide / 2-methyl-propan-2-ol; H2O / 45 h / Ambient temperature
2: 1.) n-butyltin oxide, 2.) tetra n-butylammonium iodide, 3.) NaH / 1.) MeOH, reflux, 2 h, 2.) toluene, reflux, 22 h, 3.) DME, RT, 1 h
With
osmium(VIII) oxide; tetra-(n-butyl)ammonium iodide; monobutyltin oxide; sodium hydride; 4-methylmorpholine N-oxide;
In
water; tert-butyl alcohol;
DOI:10.1021/jo00244a022
- Guidance literature:
-
With
tetra-(n-butyl)ammonium iodide; monobutyltin oxide; sodium hydride;
Yield given. Multistep reaction;
1.) MeOH, reflux, 2 h, 2.) toluene, reflux, 22 h, 3.) DME, RT, 1 h;
DOI:10.1021/jo00244a022
