Benzene, [(1-cyclopenten-1-yloxy)methyl]-

Base Information

Chemical Name:Benzene, [(1-cyclopenten-1-yloxy)methyl]-
CAS No.:113548-17-7
Molecular Formula:C12H14O
Molecular Weight:174.243
Hs Code.:
DSSTox Substance ID:DTXSID50438152
Nikkaji Number:J623.058J
Wikidata:Q82253795
Mol file:113548-17-7.mol

Synonyms:1-(Benzyloxy)cyclopentene;113548-17-7;Benzene, [(1-cyclopenten-1-yloxy)methyl]-;SCHEMBL6327555;1-cyclopentenyloxy-methyl-benzene;DTXSID50438152;[(1-cyclopenten-1-yloxy)methyl]benzene

Suppliers and Price of Benzene, [(1-cyclopenten-1-yloxy)methyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Benzene, [(1-cyclopenten-1-yloxy)methyl]-

Chemical Property:

XLogP3:2.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:174.104465066
Heavy Atom Count:13
Complexity:178

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC=C(C1)OCC2=CC=CC=C2

Technology Process of Benzene, [(1-cyclopenten-1-yloxy)methyl]-

There total 2 articles about Benzene, [(1-cyclopenten-1-yloxy)methyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: [1-Eth-(Z)-ylidene-hex-5-enyloxymethyl]-benzene

: 113548-17-7
1-(benzyloxy)cyclopentene

Guidance literature:: Mo(CHCMe2Ph)2; In pentane; at 20 ℃; for 3.5h;
DOI:10.1021/jo00094a002

Reference yield:

: 87995-27-5
benzyl hex-5-enoate

: 113548-17-7
1-(benzyloxy)cyclopentene

Guidance literature:: Multi-step reaction with 2 steps

1: 55 percent / TiCl₄, Zn, TMEDA / PbCl₂ / tetrahydrofuran / 11 h / 20 °C

2: 88 percent / Mo(CHCMe₂Ph)(NAr)(OCMe(CF₃)2)2 (Ar = 2,6-(i-Pr)2C₆H₃) / pentane / 3.5 h / 20 °C

With N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride; zinc; Mo(CHCMe2Ph)2; lead(II) chloride; In tetrahydrofuran; pentane;
DOI:10.1021/jo00094a002

Reference yield:

: 113548-17-7
1-(benzyloxy)cyclopentene

: 135357-10-7
(1S,2S)-2-(benzyloxy)cyclopentan-1-ol

: 113625-73-3
(1R,2R)-(-)-2-benzyloxycyclopentanol

Guidance literature:: 1-(benzyloxy)cyclopentene; With Pinene; diisopinocamphenylboron chloride; In tetrahydrofuran; at -15 ℃; for 120h;

With acetaldehyde; In tetrahydrofuran; at 25 ℃; for 24h;

With sodium hydroxide; dihydrogen peroxide; In tetrahydrofuran; at 25 ℃; for 6h; Title compound not separated from byproducts;
DOI:10.1016/S0022-328X(99)00047-9