1-Methyl-4,5-diphenyl-4,5-dihydro-1H-tetrazaborole

Base Information

• Chemical Name: 1-Methyl-4,5-diphenyl-4,5-dihydro-1H-tetrazaborole
• CAS No.: 114027-14-4
• Molecular Formula: C₁₃H₁₃BN₄
• Molecular Weight: 236.084
• DSSTox Substance ID: DTXSID40549509
• Wikidata: Q82428577
• Mol file: 114027-14-4.mol

Synonyms:114027-14-4;1-Methyl-4,5-diphenyl-4,5-dihydro-1H-tetrazaborole;DTXSID40549509

Chemical Property of 1-Methyl-4,5-diphenyl-4,5-dihydro-1H-tetrazaborole

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 236.1233266
• Heavy Atom Count: 18
• Complexity: 297

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B1(N(N=NN1C2=CC=CC=C2)C)C3=CC=CC=C3

Technology Process of 1-Methyl-4,5-diphenyl-4,5-dihydro-1H-tetrazaborole

There total 1 articles about 1-Methyl-4,5-diphenyl-4,5-dihydro-1H-tetrazaborole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

N-trimethylsilyl(methyl)amino-(phenyl)chloroborane (64320-05-4) + Phenyl azide (622-37-7) → 1-methyl-4,5-diphenyltetrazaborol-2-ine (114027-14-4)

Guidance literature:

In dichloromethane; soln. of azide and of N-trimethylsilylamino-chloroborane in CH2Cl2 is stirred at 40°C for 8 h (under N2); removal of the solvent provided an oily residue which is purified by column chromy. (silica gel, ether/hexane), elem. anal.;

DOI:10.1016/0022-328X(87)80222-X

upstream raw materials:

N-trimethylsilyl(methyl)amino-(phenyl)chloroborane

Phenyl azide