2-Methoxyethyl carbamate

Base Information

• Chemical Name: 2-Methoxyethyl carbamate
• CAS No.: 1616-88-2
• Molecular Formula: C4H9 N O3
• Molecular Weight: 119.12
• Hs Code.: 2924199090
• European Community (EC) Number: 216-569-5
• NSC Number: 158607
• UNII: C92CT25818
• DSSTox Substance ID: DTXSID2051766
• Nikkaji Number: J34.779E
• Wikidata: Q27275335
• Mol file: 1616-88-2.mol

Synonyms:2-Methoxyethyl carbamate;METHOXYETHYL CARBAMATE;1616-88-2;Ethanol, 2-methoxy-, carbamate;Carbamic acid, 2-methoxyethyl ester;HSDB 2595;EINECS 216-569-5;NSC 158607;BRN 1749352;UNII-C92CT25818;Ethanol, 2-methoxy-, 1-carbamate;C92CT25818;NSC-158607;4-03-00-00069 (Beilstein Handbook Reference);WLN: ZVO2O1;SCHEMBL499368;DTXSID2051766;Carbamic acid 2-methoxyethyl ester;carbamic acid-beta-methoxyethyl ester;METHOXYETHYL CARBAMATE [HSDB];MFCD01727862;NSC158607;AKOS006276825;LS-66850;Q27275335

Chemical Property of 2-Methoxyethyl carbamate

Chemical Property:

• Vapor Pressure: 0.0466mmHg at 25°C
• Melting Point: 46.8 °C
• Refractive Index: 1.4183 (estimate)
• Boiling Point: 236.7°Cat760mmHg
• PKA: 13.30±0.50(Predicted)
• Flash Point: 131°C
• PSA: 61.55000
• Density: 1.102g/cm³
• LogP: 0.42840
• XLogP3: -0.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 119.058243149
• Heavy Atom Count: 8
• Complexity: 73.7

Purity/Quality:

99% ^*data from raw suppliers

2-METHOXYETHYL CARBAMATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Carbamic Acid Esters
• Canonical SMILES: COCCOC(=O)N

Technology Process of 2-Methoxyethyl carbamate

There total 3 articles about 2-Methoxyethyl carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

→ 2-methoxyethyl carbamate (1616-88-2)

Guidance literature:

In dichloromethane; at 0 - 20 ℃; for 1h;

With potassium carbonate; In methanol; water;

Reference yield:

2-Methoxyethyl chloroformate (628-12-6) → 2-methoxyethyl carbamate (1616-88-2)

Guidance literature:

With ammonia; water;

DOI:10.1021/ja01279a029

Reference yield:

2-methoxy-ethanol (109-86-4,95507-80-5) + urea (57-13-6) → 2-methoxyethyl carbamate (1616-88-2)

Guidance literature:

With copper diacetate;

upstream raw materials:

2-Methoxyethyl chloroformate

2-methoxy-ethanol

urea