Chloro(diphenyl)[(propan-2-yl)oxy]silane

Base Information

• Chemical Name: Chloro(diphenyl)[(propan-2-yl)oxy]silane
• CAS No.: 114058-14-9
• Molecular Formula: C15H17ClOSi
• Molecular Weight: 276.838
• DSSTox Substance ID: DTXSID30555250
• Nikkaji Number: J2.188.939C
• Wikidata: Q82436547
• Mol file: 114058-14-9.mol

Synonyms:114058-14-9;Chloro(diphenyl)[(propan-2-yl)oxy]silane;chloro-(isopropoxy)diphenylsilane;DTXSID30555250

Chemical Property of Chloro(diphenyl)[(propan-2-yl)oxy]silane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 276.0737194
• Heavy Atom Count: 18
• Complexity: 227

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)O[Si](C1=CC=CC=C1)(C2=CC=CC=C2)Cl

Technology Process of Chloro(diphenyl)[(propan-2-yl)oxy]silane

There total 1 articles about Chloro(diphenyl)[(propan-2-yl)oxy]silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

diphenylsilyl dichloride (80-10-4) + isopropyl alcohol (67-63-0,8013-70-5) → diphenylisopropoxysilyl chloride (114058-14-9)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃;

DOI:10.1021/jo00246a038

Reference yield: 88.0%

1-dodecyl alcohol (112-53-8) + diphenylisopropoxysilyl chloride (114058-14-9) → Dodecyloxy-isopropoxy-diphenyl-silane (114058-18-3)

Guidance literature:

With triethylamine; In dichloromethane; for 0.5h; Ambient temperature;

DOI:10.1021/jo00246a038

Reference yield: 63.0%

chlorobromomethane (74-97-5) + diphenylisopropoxysilyl chloride (114058-14-9) → chloromethyl(isopropoxy)diphenylsilane

Guidance literature:

With Hexamethylphosphorous triamide; In benzene; at 20 ℃; for 14h; Inert atmosphere; Reflux;

DOI:10.1007/s11172-017-1892-7

upstream raw materials:

diphenylsilyl dichloride

isopropyl alcohol

Downstream raw materials:

Dodecyloxy-isopropoxy-diphenyl-silane

Acetic acid (R)-4-{(2R,5S)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-5-methyl-tetrahydro-furan-2-yl}-4-(isopropoxy-diphenyl-silanyloxy)-pentyl ester

(1''R,2'R,4S,5'S)-4-<<(diphenylisopropoxy)silyl>oxy>-4-<5'-<1''-<(tert-butyldimethylsilyl)oxy>ethyl>-2',3',4',5'-tetrahydro-5'-methylfuran-2'-yl>pentyl ethanoate