Technology Process of Cyclopentanol, 2-(5-methyl-2-nitrophenoxy)-, cis-
There total 5 articles about Cyclopentanol, 2-(5-methyl-2-nitrophenoxy)-, cis- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium salt of 5-methyl-2-nitrophenol;
In
N,N-dimethyl-formamide;
for 20h;
Heating;
DOI:10.1021/ja00218a034
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 72 percent / potassium 5-methyl-2-nitrophenoxide / dimethylformamide / 20 h / Heating
2: 80 percent / pyridinium chlorochromate / CH2Cl2 / 16 h / Ambient temperature
3: 1.) LS-Selectride; 2.) KOH, 30percent H2O2 / 1.) THF, -78 deg C, 2 h.; 2.) THF, ethanol, water, room temp.
With
potassium hydroxide; dihydrogen peroxide; potassium salt of 5-methyl-2-nitrophenol; lithium tri-sec-butyl(hydrido)borate; pyridinium chlorochromate;
In
dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00218a034
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 72 percent / potassium 5-methyl-2-nitrophenoxide / dimethylformamide / 20 h / Heating
2: 80 percent / pyridinium chlorochromate / CH2Cl2 / 16 h / Ambient temperature
3: 1.) LS-Selectride; 2.) KOH, 30percent H2O2 / 1.) THF, -78 deg C, 2 h.; 2.) THF, ethanol, water, room temp.
With
potassium hydroxide; dihydrogen peroxide; potassium salt of 5-methyl-2-nitrophenol; lithium tri-sec-butyl(hydrido)borate; pyridinium chlorochromate;
In
dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00218a034
