Hydrazinecarbodithioic acid, 1-methyl-, methyl ester

Base Information

• Chemical Name: Hydrazinecarbodithioic acid, 1-methyl-, methyl ester
• CAS No.: 20184-94-5
• Molecular Formula: C3H8N2S2
• Molecular Weight: 136.242
• Hs Code.: 2930909090
• NSC Number: 147433
• UNII: HY9ZD6SWB5
• DSSTox Substance ID: DTXSID80174016
• Nikkaji Number: J101.226F
• Wikidata: Q83044067
• Mol file: 20184-94-5.mol

Synonyms:20184-94-5;Hydrazinecarbodithioic acid, 1-methyl-, methyl ester;Methyl 2-methyldithiocarbazate;methyl N-amino-N-methylcarbamodithioate;Carbazic acid, 2-methyldithio-, methyl ester;2-Methyldithiocarbazic acid, methyl ester;NSC-147433;{METHYL[(METHYLSULFANYL)METHANETHIOYL]AMINO}AMINE;HY9ZD6SWB5;SCHEMBL4601049;DTXSID80174016;NSC147433;NSC 147433;2-Methyldithiocarbazic acid methyl ester;Methyl 1-methylhydrazinecarbodithioate #;methyl N-azanyl-N-methyl-carbamodithioate;1-Methylhydrazinecarbodithioic acid methyl ester;2-Methyl-1,1-dithiocarbazic acid methyl ester;N-Methylhydrazinecarbodithioic acid methyl ester;N-amino-N-methylcarbamodithioic acid methyl ester;A814311

Chemical Property of Hydrazinecarbodithioic acid, 1-methyl-, methyl ester

Chemical Property:

• Vapor Pressure: 0.237mmHg at 25°C
• Boiling Point: 206.5°Cat760mmHg
• Flash Point: 78.7°C
• PSA: 86.65000
• Density: 1.262g/cm³
• LogP: 1.14010
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 136.01289061
• Heavy Atom Count: 7
• Complexity: 73.3

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C(=S)SC)N

Technology Process of Hydrazinecarbodithioic acid, 1-methyl-, methyl ester

There total 7 articles about Hydrazinecarbodithioic acid, 1-methyl-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

methyl (3,5-diamino-1,2,4-triazol-1-yl)dithiocarbonate (131023-09-1) + methylhydrazine (60-34-4) → guanazole (1455-77-2) + N-methyl-hydrazinecarbodithioic acid methyl ester (20184-94-5) + 3,5-Diamino-[1,2,4]triazole-1-carbothioic acid N-methyl-hydrazide

Guidance literature:

In methanol; for 1h; Yields of byproduct given; Ambient temperature;

Reference yield: 63.0%

methyl [5-(4-chlorobenzylamino)-3-morpholino-1H-1,2,4-triazol-1-yl]carbodithioate + methylhydrazine (60-34-4) → N-methyl-hydrazinecarbodithioic acid methyl ester (20184-94-5) + (4-Chloro-benzyl)-(5-morpholin-4-yl-2H-[1,2,4]triazol-3-yl)-amine + 5-(4-Chloro-benzylamino)-3-morpholin-4-yl-[1,2,4]triazole-1-carbothioic acid N-methyl-hydrazide

Guidance literature:

In methanol; for 5h; Yields of byproduct given; Ambient temperature;

Reference yield: 63.0%

methyl (5-benzylamino-3-morpholino-1,2,4-triazol-1-yl)dithiocarbonate (131023-16-0) + methylhydrazine (60-34-4) → N-methyl-hydrazinecarbodithioic acid methyl ester (20184-94-5) + 5-benzylamino-3-morpholino-1H-1,2,4-triazole (113362-43-9) + 5-Benzylamino-3-morpholin-4-yl-[1,2,4]triazole-1-carbothioic acid N'-methyl-hydrazide + 1-(5-benzylamino-3-morpholino-1H-1,2,4-triazol-1-yl)-N'-methylcarbothiohydrazide

Guidance literature:

In methanol; for 4h; Ambient temperature;

upstream raw materials:

methyl (3,5-diamino-1,2,4-triazol-1-yl)dithiocarbonate

methylhydrazine

methyl (5-amino-3-methylthio-1,2,4-triazol-1-yl)dithiocarbonate

Methyl (3-dimethylamino-5-amino-1H-1,2,4-triazol-1-yl)dithiocarbonate

Downstream raw materials:

benzylidene-methyl-dithiocarbazic acid methyl ester

4-(4-Chloro-phenyl)-5-(4-chloro-phenylamino)-2-methyl-2,4-dihydro-[1,2,4]triazole-3-thione

N',N-Bis(4-chlorophenyl)-N-guanidine

N-Methyl-N'-(4-methyl-benzoyl)-hydrazinecarbodithioic acid methyl ester

Refernces