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Methylhydrazine

Base Information Edit
  • Chemical Name:Methylhydrazine
  • CAS No.:60-34-4
  • Molecular Formula:CH6N2
  • Molecular Weight:46.072
  • Hs Code.:29280000
  • European Community (EC) Number:200-471-4
  • ICSC Number:0180
  • UN Number:1244
  • UNII:UWA30B5Z1J
  • DSSTox Substance ID:DTXSID4020874
  • Nikkaji Number:J2.338H
  • Wikipedia:Monomethylhydrazine
  • Wikidata:Q417347
  • ChEMBL ID:CHEMBL160520
  • Mol file:60-34-4.mol
Methylhydrazine

Synonyms:Methylhydrazine;Monomethylhydrazine

 This product is a nationally controlled contraband, and the Lookchem platform doesn't provide relevant sales information.

Chemical Property of Methylhydrazine Edit
Chemical Property:
  • Appearance/Colour:colourless liquid with an ammonia-like odour 
  • Vapor Pressure:37.5 mm Hg ( 20 °C) 
  • Melting Point:-21 °C 
  • Refractive Index:n20/D 1.4325(lit.)  
  • Boiling Point:87.5 °C at 760 mmHg 
  • PKA:8.84±0.70(Predicted) 
  • Flash Point:21.1 °C 
  • PSA:38.05000 
  • Density:0.8 g/cm3 
  • LogP:0.17070 
  • Storage Temp.:Flammables area 
  • Solubility.:Soluble in alcohol and ether (Weast, 1986) 
  • Water Solubility.:soluble 
  • XLogP3:-0.9
  • Hydrogen Bond Donor Count:2
  • Hydrogen Bond Acceptor Count:2
  • Rotatable Bond Count:0
  • Exact Mass:46.053098200
  • Heavy Atom Count:3
  • Complexity:2.8
  • Transport DOT Label:Poison Inhalation Hazard Flammable Liquid Corrosive
Purity/Quality:
Safty Information:
  • Pictogram(s): FlammableF, VeryT+, DangerousN, Toxic
  • Hazard Codes:F,T+,N,T 
  • Statements: 11-24/25-26-34-40-51/53-45-23/24/25-50/53 
  • Safety Statements: 16-26-28-36/37/39-45-60-53-24/25-61 
MSDS Files:

SDS file from LookChem

Useful:
  • Chemical Classes:Toxic Gases & Vapors -> Other Toxic Gases & Vapors
  • Canonical SMILES:CNN
  • Inhalation Risk:A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20 °C.
  • Effects of Short Term Exposure:The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. The substance may cause effects on the central nervous system, liver and blood. This may result in liver impairment and the formation of methaemoglobin. Exposure far above the OEL could cause death. The effects may be delayed. Medical observation is indicated.
  • Effects of Long Term Exposure:The substance may have effects on the liver and blood. This may result in liver impairment and the formation of methaemoglobin. This substance is possibly carcinogenic to humans.
  • Description Methyl hydrazine, CH3NHNH2, is a colorless, hygroscopic liquid with an ammonia-like odor. It is soluble in water, with a specific gravity of 0.87, which is lighter than water. Methyl hydrazine is toxic by inhalation and ingestion, and is a suspected human carcinogen. The TLV ceiling is 0.2 ppm in air, and the IDLH is 50 ppm. The target organs are the central nervous system, respiratory system, liver, blood, eyes, and cardiovascular system. The four-digit UN identification number is 1244. The NFPA 704 designation is health 4, flammability 3, and reactivity 2. The primary uses are as a missile propellant and a solvent.
  • Physical properties Fuming, clear, colorless liquid with an ammonia-like odor. Odor threshold concentrations ranged from 1 to 3 ppm (quoted, Keith and Walters, 1992).
  • Uses Methylhydrazine is used in missile propellants and as a solvent and chemical intermediate. Rocket fuel; solvent; chemical intermediate Missile propellant, intermediate, solvent.
Technology Process of Methylhydrazine

There total 53 articles about Methylhydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.2%

Guidance literature:
With sodium tosylate; hydrazine hydrate; sodium hydrogensulfite; at 75 ℃; for 4h; Temperature; Autoclave;
Guidance literature:
With sodium acetate; In methanol; water; for 24h; Electrolysis;
Guidance literature:
With hydrogenchloride; hydrazine hydrate; In ethanol; at 73 ℃; for 2.3h; Concentration; Temperature;