L-Galactose, 6-deoxy-2-O-methyl-

Base Information

Chemical Name:L-Galactose, 6-deoxy-2-O-methyl-
CAS No.:34299-00-8
Molecular Formula:C₇H₁₄O₅
Molecular Weight:178.185
Hs Code.:
UNII:FB6U9V9D8O
DSSTox Substance ID:DTXSID201316797
Nikkaji Number:J385.999A
Mol file:34299-00-8.mol

Synonyms:2-O-methylfucose

Suppliers and Price of L-Galactose, 6-deoxy-2-O-methyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of L-Galactose, 6-deoxy-2-O-methyl-

Chemical Property:

Vapor Pressure:1.4E-07mmHg at 25°C
Boiling Point:386.8°Cat760mmHg
Flash Point:159.7°C
Density:1.256g/cm³
XLogP3:-1.8
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:5
Exact Mass:178.08412354
Heavy Atom Count:12
Complexity:138

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C(C(C(C=O)OC)O)O)O
Isomeric SMILES:C[C@@H]([C@H]([C@H]([C@@H](C=O)OC)O)O)O

Technology Process of L-Galactose, 6-deoxy-2-O-methyl-

There total 12 articles about L-Galactose, 6-deoxy-2-O-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 108182-36-1
allyl 2-O-methyl-α-L-fucopyranoside

: 921-90-4,4060-14-4,4060-15-5,17212-17-8,22350-97-6,29839-06-3,56192-98-4,88853-34-3,34299-00-8
2-O-methyl-L-fucose

Guidance literature:: With methanol; palladium dichloride; In dichloromethane; at 20 ℃; for 24h; Inert atmosphere;
DOI:10.3762/bjoc.12.282

Reference yield:

O-polysaccharide of the lipopolysaccharide from Azospirillum brasilense Jm₆B₂: O-polysaccharide of the lipopolysaccharide from Azospirillum brasilense Jm₆B₂

: 74-88-4
methyl iodide

: 6778-35-4,7459-37-2,13403-20-8,39951-09-2,101468-34-2,4153-29-1
2,3-di-O-methylxylose

: 921-90-4,4060-14-4,4060-15-5,17212-17-8,22350-97-6,29839-06-3,56192-98-4,88853-34-3,34299-00-8
2-O-methyl-L-fucose

: 6-deoxy-3,4-di-O-methylhexose

: 149655-76-5,18546-13-9
6-deoxy-3-O-methylhexose

: 2,3,4,6-tetra-O-methylhexose

: 2,3-di-O-methylhexose

: 890026-66-1
2,3,4-tri-O-methylrhamnose

Guidance literature:: O-polysaccharide of the lipopolysaccharide from Azospirillum brasilense Jm₆B₂; methyl iodide; With sodium hydroxide; In dimethyl sulfoxide;

With water; trifluoroacetic acid; at 100 ℃; for 2h;
DOI:10.1016/j.carres.2012.04.006

Reference yield:

: 108182-34-9
allyl 3,4-di-O-isopropylidene-α-L-fucopyranoside

: 921-90-4,4060-14-4,4060-15-5,17212-17-8,22350-97-6,29839-06-3,56192-98-4,88853-34-3,34299-00-8
2-O-methyl-L-fucose

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h / 0 °C

1.2: 0.5 h / 0 °C

2.1: acetic acid; water / 0.5 h / 90 °C

3.1: palladium dichloride; methanol / dichloromethane / 24 h / 20 °C / Inert atmosphere

With methanol; water; sodium hydride; acetic acid; palladium dichloride; In dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.3762/bjoc.12.282