Technology Process of Cyclohexene, 1,2-diiodo-
There total 4 articles about Cyclohexene, 1,2-diiodo- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
1,2-dibromocyclohex-1-ene;
With
chloro-trimethyl-silane; indium(III) bromide; aluminium; lithium chloride;
In
tetrahydrofuran;
at 50 ℃;
for 12h;
Inert atmosphere;
With
iodine;
at 0 ℃;
for 1h;
Inert atmosphere;
DOI:10.1002/anie.201205169
- Guidance literature:
-
With
N,N,N′,N′-tetramethyl-N″-tert-butylguanidine; iodine;
In
dichloromethane;
at 90 ℃;
for 4h;
DOI:10.1016/S0040-4020(01)85102-4
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: phosphorus pentachloride / chloroform / 4 h / 0 °C / Reflux
1.2: 0.17 h / -5 °C
2.1: potassium hydroxide / methanol / 3 h / Reflux
3.1: potassium iodide; copper(l) iodide / 15 h / 120 °C
With
copper(l) iodide; phosphorus pentachloride; potassium iodide; potassium hydroxide;
In
methanol; chloroform;
