Gallium trifluoride [MI]

Base Information

• Chemical Name: Gallium trifluoride [MI]
• CAS No.: 7783-51-9
• Molecular Formula: F3Ga
• Molecular Weight: 126.718
• Hs Code.: 2826199090
• UNII: 3EG50JLZ49
• Nikkaji Number: J95.947B
• Mol file: 7783-51-9.mol

Synonyms:MFCD00011021;F3Ga;F3-Ga;GALLIUM TRIFLUORIDE [MI];Gallium(III) fluoride, anhydrous;FT-0626601;A839216;Gallium(III) Fluoride;Trifluorogallane;Gallium Fluoride (Gaf3)

Chemical Property of Gallium trifluoride [MI]

Chemical Property:

• Appearance/Colour: colorless needle crystalline
• Vapor Pressure: 922mmHg at 25°C
• Melting Point: 800°C
• Boiling Point: 19.5 °C at 760 mmHg
• Flash Point: 1000°C
• PSA: 0.00000
• Density: 4.47 g/mL at 25 °C(lit.)
• LogP: 0.87980
• Sensitive.: Moisture Sensitive
• Water Solubility.: Soluble in water (0.02g/L at 200C).
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 125.92078
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Gallium(III) fluoride 99.0% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,Xi
• Hazard Codes: Xn,Xi
• Statements: 20/21/22
• Safety Statements: 36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [F-].[F-].[F-].[Ga+3]
• Uses: Employed in the preparation and study of optical fluorogallate glasses.1 Gallium(III) fluoride reacts with mineral acids to give hydrofluoric acid. It is used in the preparation and study of optical fluorogallate glasses.

Technology Process of Gallium trifluoride [MI]

There total 16 articles about Gallium trifluoride [MI] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

gallium(III) fluoride trihydrate → gallium trifluoride (7783-51-9)

Guidance literature:

In neat (no solvent); heating GaF3*3H2O in flowing F2;; product contains always oxide;;

Reference yield:

gallium (7440-55-3) + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) → gallium trifluoride (7783-51-9)

Guidance literature:

With H₂O₂; In water; Ga was reacted with excessive hydrofluoric acid under N2 flow, heated on water-bath, H2O2 was gradually added; product was vaporized until dry on water-bath, residue was heated at 200°C for 2 h under HF flow; X-ray diffraction;

DOI:10.1016/S0040-6031(00)00596-7

Reference yield:

ammonium hexafluorogallate(III) → gallium trifluoride (7783-51-9)

Guidance literature:

With F₂; In neat (no solvent); heating (N2:F2 atm. 5:1; 400°C, 5 d);

DOI:10.1002/zaac.19966220216

upstream raw materials:

hydrogen fluoride

fluorine

gallium

boron trifluoride

Downstream raw materials:

gallium phosphide

Refernces

• 1、 Dahlke,Pehler,Babel. "Structural and magnetochemical studies on KCuGaF6". . p. 115 - 121. Retrieved 2005.
• 2、 Wang, Xuefeng,Andrews, Lester. "Quantum-chemical calculations and IR spectra of the (F2)MF 2 molecules (M = B, Al, Ga, In, Tl) in solid matrices: A new class of very high electron affinity neutral molecules". . p. 3768 - 3771. Retrieved 2011/04/26.