(Z)-1-BroMo-4-(2-broMovinyl)benzene

Base Information

• Chemical Name: (Z)-1-BroMo-4-(2-broMovinyl)benzene
• CAS No.: 115665-68-4
• Molecular Formula: C₈H₆Br₂
• Molecular Weight: 261.944
• Hs Code.: 2903999090
• Mol file: 115665-68-4.mol

Synonyms:(E-)-1-bromo-3,3,3-trifluoroprop-1-ene;1-bromo-3,3,3,trifluoro-1-propene;1-bromo-4-((E)-2-bromovinyl)benzene;(E)-1-[2-bromovinyl]-4-bromobenzene;1-Propene,1-bromo-3,3,3-trifluoro-,(1E);(E)-1-bromo-4-(2-bromovinyl)benzene;1-Bromo-3,3,3-trifluoropropane;

Chemical Property of (Z)-1-BroMo-4-(2-broMovinyl)benzene

Chemical Property:

• PSA: 0.00000
• LogP: 3.81470
• Storage Temp.: 2-8°C

Purity/Quality:

98.5% ^*data from raw suppliers

(Z)-1-Bromo-4-(2-bromovinyl)benzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (Z)-1-BroMo-4-(2-broMovinyl)benzene

There total 41 articles about (Z)-1-BroMo-4-(2-broMovinyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(2RS,3SR)-2,3-dibromo-3-(4-bromophenyl)propanoic acid (112595-55-8) → (E)-1-bromo-4-(2-bromovinyl)benzene (115665-68-4,115665-77-5)

Guidance literature:

With silver(I) acetate; In acetic acid; for 0.0166667h; microwave irradiation;

DOI:10.1016/j.tet.2004.10.102

Reference yield: 94.5%

(2RS,3SR)-2,3-dibromo-3-(4-bromophenyl)propanoic acid (112595-55-8) → (Z)-1-[2-bromovinyl]-4-bromobenzene (115665-77-5,115665-68-4)

Guidance literature:

With pyridinium chlorochromate; In dichloromethane;

DOI:10.1021/acs.joc.0c01612

Reference yield: 92.0%

C9H6Br2O2 → (Z)-1-[2-bromovinyl]-4-bromobenzene (115665-77-5,115665-68-4)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 20 ℃; Cooling with ice;

DOI:10.1016/j.tetlet.2017.08.069

upstream raw materials:

bromocyclooctatetraene

2,3-Dibromo-3-(4-bromophenyl)propionic acid

(2RS,3SR)-2,3-dibromo-3-(4-bromophenyl)propanoic acid

Bromoform

Downstream raw materials:

(S,E)-(+)-tert-butyl 2-cinnamyl-4,4-dimethylpyrrolidine-1-carboxylate

C₁₇H₁₂BrNO₂

2-[(E)-2-(4-bromophenyl)ethenyl]tetrahydrofuran

(R,Z)-(+)-tert-butyl 2-(3-phenylallyl)pyrrolidine-1-carboxylate