112595-55-8Relevant articles and documents
Chloro/bromotrimethylsilane-Cu(NO3)2·3H2O: Safe and efficient reagent system for the decarboxylative ipso-nitration and dibromination of cinnamic acids
Roshandel, Sahar,Gurung, Laxman,Mathew, Thomas,Prakash, G.K. Surya
supporting information, p. 2842 - 2845 (2017/06/27)
Further synthetic potential of halotrimethylsilane-nitrate salt mixture is revealed. A mixture of TMSX-Cu(NO3)2·3H2O system is found to be an efficient reagent system for both the decarboxylative nitration (ipso-nitration) when X?=?Cl, and dibromination of cinnamic acids, with X?=?Br, under mild conditions. The reactions are safe and simple, affording the corresponding products (E)-β-nitrostyrenes, and anti-2,3-dibromo-3-phenylpropanoic acids in high yields with high selectivity in a relatively short time. Use of hazardous and toxic nitrating systems such as acetyl nitrate and brominating agents such as molecular bromine can be avoided.
Convenient synthesis of terminal alkynes from anti-3-aryl-2,3- dibromopropanoic acids using a K2CO3/DMSO system
Cheng, Xuezhi,Jia, Jun,Kuang, Chunxiang
experimental part, p. 2350 - 2354 (2012/02/03)
A convenient, efficient, and generally applicable method was developed for the synthesis of terminal alkynes from anti-3-aryl-2,3-dibromopropanoic acids in the presence of DMSO and K2CO3.
Stereoselective synthesis of (E)-β-arylvinyl bromides by microwave-induced reaction of anti-3-aryl-2,3-dibromopropanoic acids using an AgOAc-AcOH system
Kuang, Chunxiang,Senboku, Hisanori,Tokuda, Masao
, p. 637 - 642 (2007/10/03)
(E)-β-Arylvinyl bromides were stereoselectively prepared in high yields by microwave irradiation of the corresponding anti-3-aryl-2,3- dibromopropanoic acids in AcOH in the presence of AgOAc for 0.5-3.0 min. (E)-β-Arylvinyl bromides were stereoselectively prepared in high yields by microwave irradiation of the corresponding anti-3-aryl-2,3-dibromo-propanoic acids in AcOH in the presence of AgOAc for 0.5-3.0 min.