Diethyl 2,3-dihydro-1H-indene-1,1-dicarboxylate

Base Information

• Chemical Name: Diethyl 2,3-dihydro-1H-indene-1,1-dicarboxylate
• CAS No.: 115860-31-6
• Molecular Formula: C15H18O4
• Molecular Weight: 262.306
• DSSTox Substance ID: DTXSID30558281
• Nikkaji Number: J601.867J
• Wikidata: Q82440524

Synonyms:115860-31-6;Diethyl 2,3-dihydro-1H-indene-1,1-dicarboxylate;diethyl 1,1-indanedicarboxylate;DTXSID30558281;2,3-dihydro-indene-1,1-dicarboxylic acid diethyl ester

Chemical Property of Diethyl 2,3-dihydro-1H-indene-1,1-dicarboxylate

Chemical Property:

• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 262.12050905
• Heavy Atom Count: 19
• Complexity: 332

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCOC(=O)C1(CCC2=CC=CC=C21)C(=O)OCC

Technology Process of Diethyl 2,3-dihydro-1H-indene-1,1-dicarboxylate

There total 5 articles about Diethyl 2,3-dihydro-1H-indene-1,1-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

ethyl 2-(ethoxycarbonyl)-4-phenylbutanoate (6628-68-8) → diethyl α-(2-phenylethyl)-α-hydroxymalonate (118598-70-2) + Indan-1,1-dicarboxylic acid diethyl ester (115860-31-6) + 2-Nitro-2-phenethyl-malonic acid diethyl ester

Guidance literature:

With ammonium cerium(IV) nitrate; In acetic acid; at 80 ℃; for 3h; Product distribution; Mechanism; further reagents, temperatures, solvents; also further ω-phenylalkyldicarbonyl compounds;

DOI:10.1002/ardp.19943270809

Reference yield: 39.0%

ethyl 2-(ethoxycarbonyl)-4-phenylbutanoate (6628-68-8) → 2-(2-Acetoxy-2-phenyl-ethyl)-malonic acid diethyl ester (118598-71-3) + 1,1-dicarbethoxy-3-acetoxyindan (118629-54-2) + tetraethyl 1,2-bis(phenylethyl)-1,1,2,2-ethanetetracarboxylate (118598-64-4) + Indan-1,1-dicarboxylic acid diethyl ester (115860-31-6)

Guidance literature:

With sodium acetate; manganese triacetate; In acetic acid; at 70 ℃; for 8h;

DOI:10.1021/jo00272a047

Reference yield: 39.0%

ethyl 2-(ethoxycarbonyl)-4-phenylbutanoate (6628-68-8) + Mangantriacetat → 2-(2-Acetoxy-2-phenyl-ethyl)-malonic acid diethyl ester (118598-71-3) + 1,1-dicarbethoxy-3-acetoxyindan (118629-54-2) + tetraethyl 1,2-bis(phenylethyl)-1,1,2,2-ethanetetracarboxylate (118598-64-4) + Indan-1,1-dicarboxylic acid diethyl ester (115860-31-6)

Guidance literature:

With sodium acetate; In acetic acid; at 70 ℃; for 8h;

DOI:10.1021/jo00272a047

upstream raw materials:

ethyl 2-(ethoxycarbonyl)-4-phenylbutanoate

acetic acid

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