Benzaldehyde, 4-chloro-, oxime

Base Information

• Chemical Name: Benzaldehyde, 4-chloro-, oxime
• CAS No.: 3717-23-5
• Molecular Formula: C7H6ClNO
• Molecular Weight: 155.584
• Hs Code.: 2928000090
• NSC Number: 56508
• DSSTox Substance ID: DTXSID90417744
• Nikkaji Number: J119.238H,J124.208C
• Mol file: 3717-23-5.mol

Synonyms:p-Chloro-anti-benzaldoxime;anti-p-Chlorobenzaldoxime;(Z)-4-Chlorobenzaldoxime;3717-23-5;Benzaldehyde, p-chloro-, oxime, (Z)-;Benzaldehyde, 4-chloro-, oxime, (Z)-;(E)-4-Chlorobenzaldehyde oxime;Benzaldehyde, 4-chloro-, oxime;4-Chlorobenzaldehydeoxime;4-Chlorobenzaldoxime;Benzaldehyde, p-chloro-, oxime, (E)-;Benzaldehyde, 4-chloro-, oxime, (E)-;z-p-chlorobenzaldoxime;(E)-N-[(4-chlorophenyl)methylidene]hydroxylamine;cis-4-Chlorobenzaldehyde oxime;SCHEMBL2161959;DTXSID90417744;NSC56508;NSC-56508;W10410;N-[(Z)-(4-Chlorophenyl)methylidene]hydroxylamine

Chemical Property of Benzaldehyde, 4-chloro-, oxime

Chemical Property:

• Vapor Pressure: 0.0314mmHg at 25°C
• Boiling Point: 233.2°Cat760mmHg
• Flash Point: 94.8°C
• PSA: 32.59000
• Density: 1.21g/cm³
• LogP: 2.14810
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 155.0137915
• Heavy Atom Count: 10
• Complexity: 119

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1C=NO)Cl
• Isomeric SMILES: C1=CC(=CC=C1/C=N\O)Cl

Technology Process of Benzaldehyde, 4-chloro-, oxime

There total 7 articles about Benzaldehyde, 4-chloro-, oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

4-chlorobenzaldehyde (104-88-1) → (Z)-p-chlorobenzaldehyde oxime (3717-23-5)

Guidance literature:

With hydroxylamine hydrochloride; for 0.0833333h; Reflux; Neat (no solvent);

Reference yield: 90.0%

4-chlorobenzaldehyde (104-88-1) → (Z)-p-chlorobenzaldehyde oxime (3717-23-5) + 4-chlorobenzaldehyde oxime (3717-24-6)

Guidance literature:

With hydroxylamine hydrochloride; zinc(II) oxide; at 80 ℃; for 0.0833333h;

DOI:10.1055/s-2002-31964

Reference yield: 80.0%

4-chlorobenzaldehyde oxime (3717-24-6) → (Z)-p-chlorobenzaldehyde oxime (3717-23-5)

Guidance literature:

With hydrogenchloride; In water;

DOI:10.1016/S0040-4020(02)00835-9

upstream raw materials:

4-chlorobenzaldehyde oxime

4-chloro-benzaldehyde-(O-acetyl-seqcis-oxime )

4-chlorobenzaldehyde

benzene

Downstream raw materials:

4-chlorobenzaldehyde oxime

4-Cyanochlorobenzene

4-chloro-benzaldehyde-(O-acetyl-seqcis-oxime )

3-(4-chloro-phenyl)-5-(2,2,2-trifluoro-1-trifluoromethyl-ethylidene)-[1,4,2]oxathiazolidine