Fenthion sulfone

Base Information

• Chemical Name: Fenthion sulfone
• CAS No.: 3761-42-0
• Molecular Formula: C₁₀H₁₅O₅PS₂
• Molecular Weight: 310.332
• European Community (EC) Number: 634-861-4
• DSSTox Substance ID: DTXSID6041975
• Nikkaji Number: J8.243K
• Wikidata: Q63396464
• Mol file: 3761-42-0.mol

Synonyms:Fenthion sulfone;Fenthion-sulfone;3761-42-0;Fenthione sulfone;O,O-Dimethyl O-(4-(methylsulfonyl)-m-tolyl) phosphorothioate;O,O-Dimethyl O-((4-methylthio)-m-tolyl)phosphorothioate sulfone;O,O-Dimethyl O-(3-methyl-4-(methylsulfonyl)phenyl) phosphorothioate;dimethoxy-(3-methyl-4-methylsulfonylphenoxy)-sulfanylidene-lambda5-phosphane;Phosphorothioic acid, O,O-dimethyl O-(3-methyl-4-(methylsulfonyl)phenyl) ester;Phosphorothioic acid, O,O-dimethyl O-[3-methyl-4-(methylsulfonyl)phenyl] ester;Phosphorothioic acid, O,O-dimethyl O-[4-(methylsulfonyl)-m-tolyl] ester;PHOSPHOROTHIOIC ACID, O,O-DIMETHYL O-(4-(METHYLSULFONYL)-m-TOLYL) ESTER;dimethoxy-(3-methyl-4-methylsulfonylphenoxy)-sulfanylidene-?^{5}-phosphane;DTXSID6041975;SCHEMBL23646028;C10H15O5PS2;C10-H15-O5-P-S2;AKOS015903360;LS-108856;Fenthion-sulfone 1000 microg/mL in Acetone;Fenthion-sulfone 100 microg/mL in Ethyl acetate;Fenthion-sulfone, PESTANAL(R), analytical standard;Q63396464;O,O-Dimethyl o-[3-methyl-4-(methylsulfonyl)phenyl] thiophosphate #;m-Cresol, 4-(methylsulfonyl)-, O-ester with O,O-dimethyl phosphorothioate;Phosphorothioic acid, O,O-dimethyl O-(3-methyl-4-(methylsulfonyl)phenyl) ester (9CI)

Chemical Property of Fenthion sulfone

Chemical Property:

• Vapor Pressure: 7.54E-07mmHg at 25°C
• Melting Point: 77～79℃
• Boiling Point: 419.2°Cat760mmHg
• Flash Point: 207.3°C
• PSA: 112.11000
• Density: 1.333g/cm³
• LogP: 4.02600
• Storage Temp.: 2-8°C
• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 5
• Exact Mass: 310.00985292
• Heavy Atom Count: 18
• Complexity: 409

Purity/Quality:

98%Min ^*data from raw suppliers

FenthionSulfone ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T,N
• Statements: 25-50/53
• Safety Statements: 45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC1=C(C=CC(=C1)OP(=S)(OC)OC)S(=O)(=O)C
• Uses: Fenthion Sulfone is a metabolite of the organothiophosphate insecticide Fenthion (F278000).

Technology Process of Fenthion sulfone

There total 2 articles about Fenthion sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

fenthion (55-38-9) → Fenthion sulfone (3761-42-0)

Guidance literature:

With potassium permanganate; In water; acetic acid; for 12h;

DOI:10.1016/S0045-6535(00)00042-4

Reference yield:

fenthion (55-38-9) → (+)-Fenthion sulfoxide (3761-41-9) + Fenthion oxon (6552-12-1) + Fenthion sulfone (3761-42-0) + fenthion oxon sulfoxide (6552-13-2)

Guidance literature:

With water; In phosphate buffer; at 25 ℃; pH=7; Further Variations:; pH-values; Temperatures; Thermodynamic data;

DOI:10.1021/jf9907539

upstream raw materials:

fenthion

Refernces

• 1、 Huang, Jiping,Mabury, Scott A.. "Hydrolysis kinetics of fenthion and its metabolites in buffered aqueous media". . p. 2582 - 2588. Retrieved 2007/10/03.