3H-Diazirine, 3-methoxy-3-(4-methylphenyl)-

Base Information

Chemical Name:3H-Diazirine, 3-methoxy-3-(4-methylphenyl)-
CAS No.:116548-92-6
Molecular Formula:C₉H₁₀N₂O
Molecular Weight:162.191
Hs Code.:
Mol file:116548-92-6.mol

Synonyms:

Suppliers and Price of 3H-Diazirine, 3-methoxy-3-(4-methylphenyl)-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3H-Diazirine, 3-methoxy-3-(4-methylphenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 3H-Diazirine, 3-methoxy-3-(4-methylphenyl)-

There total 1 articles about 3H-Diazirine, 3-methoxy-3-(4-methylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 124-41-4
sodium methylate

: 95911-62-9
3-Bromo-3-(p-methylphenyl)diazirine

: 116548-92-6
methoxy(4-methylphenyl)diaziridine

Guidance literature:: In N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl acetamide;
DOI:10.1039/DT9910001417

Reference yield: 77.0%

: [(η5-C5Me5)Co(μ-CO)]2

: 116548-92-6
methoxy(4-methylphenyl)diaziridine

: di-μ-carbonyl-μ-methoxy(4-methylphenyl)methylene-bis{(η5-pentamethylcyclopentadienyl)cobalt}

Guidance literature:: In dichloromethane; pentane; addn. of methoxy(4-methylphenyl)diazirine soln. dropwise for 2.5 h by rapidly stirring under dry nitrogen with rigorous exclusion of light to cobalt compound; then stirring again for 2 h; solvent removed under reduced pressure; recrystn. from EtOH twice at -78°C, dried in vac.; elem. anal.;;

Reference yield: 65.0%

: Cp*2Rh₂(CO)2

: 116548-92-6
methoxy(4-methylphenyl)diaziridine

: {(η5-C5Me5)2Rh2(CO)2(μ-C(4-MeC6H4)OMe)}

Guidance literature:: In dichloromethane; pentane; a cooled (-30°C) pentane soln. of the diazirine was added dropwise to a CH2Cl2 soln. of the Rh-complex at room temp. over 3-4 h; solvent was evapd., residue was crystd. from CH2Cl2-EtOH at -78°C;
DOI:10.1039/c39870001285