Stannane, trimethyl(1-phenylethenyl)-

Base Information

Chemical Name:Stannane, trimethyl(1-phenylethenyl)-
CAS No.:1198-01-2
Molecular Formula:C11H16Sn
Molecular Weight:266.958
Hs Code.:
DSSTox Substance ID:DTXSID80448522
Wikidata:Q82267555

Synonyms:Stannane, trimethyl(1-phenylethenyl)-;1198-01-2;DTXSID80448522

Suppliers and Price of Stannane, trimethyl(1-phenylethenyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Stannane, trimethyl(1-phenylethenyl)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:268.027403
Heavy Atom Count:12
Complexity:158

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Sn](C)(C)C(=C)C1=CC=CC=C1

Technology Process of Stannane, trimethyl(1-phenylethenyl)-

There total 3 articles about Stannane, trimethyl(1-phenylethenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 98-81-7
1-bromovinylbenzene

: 1066-45-1
trimethyltin(IV)chloride

: 1198-01-2
Me₃SnCPhCH₂

Guidance literature:: With magnesium; In tetrahydrofuran; under Ar, soln. of Br-compd. added slowly to Mg in THF with refluxing, refluxed, cooled to room temp., soln. of Me3SnCl added, stirred for several h; ether and saturated NH4Cl-soln. added, organic layer dried over MgSO4, fractionated, elem. anal.;
DOI:10.1021/om00125a015

Reference yield: 40.0%

: 28143-79-5
1-phenyl vinyl triflate

: 917-54-4
methyllithium

: tin(ll) chloride

: 1198-01-2
Me₃SnCPhCH₂

Guidance literature:: With methyl magnesium iodide; copper(l) cyanide; In tetrahydrofuran; diethyl ether; byproducts: α-methylstyrene; to soln. of MeLi in Et2O added suspn. of anhyd. SnCl2 in THF at 0 °C, after stirring for 20 min added soln. of MeMgI in Et2O at 0 °C, stirred for 15 min CuCN and soln. of alkene in THF added successively, stirred for 5 h at room temp.; poured into aq. satd. soln. of NH4Cl, extd. (Et2O), org. layer washed with brine, dried over Na2SO4, concd., cromd. (SiO2);
DOI:10.1016/0022-328X(85)87365-4