(1alpha,2beta,4beta,6alpha)-2,2,7-Trimethyl-3-oxatricyclo(4.1.1.02,4)octane

Base Information Edit

Chemical Name:(1alpha,2beta,4beta,6alpha)-2,2,7-Trimethyl-3-oxatricyclo(4.1.1.02,4)octane
CAS No.:14575-92-9
Deprecated CAS:95044-43-2
Molecular Formula:C10H16 O
Molecular Weight:152.236
Hs Code.:2932999099
European Community (EC) Number:250-938-1,305-805-3
Nikkaji Number:J269.365H
Mol file:14575-92-9.mol

Synonyms:EINECS 238-617-4;(+-)-alpha-Pinene oxide;EINECS 250-938-1;32162-27-9;3-Oxatricyclo(4.1.1.0(sup 2,4))octane, 2,7,7-trimethyl-, d-;EC 250-938-1;(1alpha,2beta,4beta,6alpha)-2,2,7-Trimethyl-3-oxatricyclo(4.1.1.02,4)octane;(1S-(1alpha,2alpha,4alpha,6alpha))-2,2,7-Trimethyl-3-oxatricyclo(4.1.1.02,4)octane;EINECS 305-805-3;(1alpha,2beta,4beta,6alpha)-2,2,7-trimethyl-3-oxatricyclo[4.1.1.02,4]octane;[1S-(1alpha,2alpha,4alpha,6alpha)]-2,2,7-trimethyl-3-oxatricyclo[4.1.1.02,4]octane;Pinane, 2,3-epoxy-, (1S,2S,3R,5S)-()-;(1alpha,2beta,4beta,6alpha)-(+-)-2,2,7-trimethyl-3-oxatricyclo[4.1.1.02,4]octane;(1alpha,2beta,4beta,6alpha)-(1)-2,2,7-Trimethyl-3-oxatricyclo(4.1.1.02,4)octane;3-Oxatricyclo[4.1.1.02,4]octane, 2,7,7-trimethyl-, [1S-(1.alpha.,2.alpha.,4.alpha.,6.alpha.)]-;95044-43-2;AKOS032437793;(1S,2S,3R,5S)-2,3-Epoxypinane;LS-99736

Suppliers and Price of (1alpha,2beta,4beta,6alpha)-2,2,7-Trimethyl-3-oxatricyclo(4.1.1.02,4)octane

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
R-ALPHA-(+)-PINENE OXIDE 95.00%
5MG
$ 501.36

Total 4 raw suppliers

Chemical Property of (1alpha,2beta,4beta,6alpha)-2,2,7-Trimethyl-3-oxatricyclo(4.1.1.02,4)octane Edit

Chemical Property:

Boiling Point:188.6°Cat760mmHg
Flash Point:65.6°C
PSA：12.53000
Density:1.027g/cm³
LogP:2.20990
XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:152.120115130
Heavy Atom Count:11
Complexity:221

Purity/Quality:

99% ^*data from raw suppliers

R-ALPHA-(+)-PINENE OXIDE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C2CC1C3(C(C2)O3)C)C
Isomeric SMILES:C[C@]12[C@H]3C[C@H](C3(C)C)C[C@H]1O2

Technology Process of (1alpha,2beta,4beta,6alpha)-2,2,7-Trimethyl-3-oxatricyclo(4.1.1.02,4)octane

There total 16 articles about (1alpha,2beta,4beta,6alpha)-2,2,7-Trimethyl-3-oxatricyclo(4.1.1.02,4)octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 80-56-8,25766-18-1
rac-α-pinene

: 1686-14-2,14575-92-9,19894-99-6,32162-27-9,38301-46-1,94063-22-6,95044-43-2,25488-94-2
2α,3α-epoxypinane

Guidance literature:: With sodium hypochlorite; manganese(II) 5,10,15,20-tetraphenylporphyrinate; 1-hexylimidazole; In dichloromethane; water; at 0 ℃; for 0.333333h; Product distribution; pH=9.5; further olefines, also in presence of methyl trioctyl ammonium chloride; selectivity;

Reference yield: 98.0%

: 7785-70-8,25766-18-1
(+)-α-pinene

: 14575-92-9,25488-94-2
2,3-epoxy-cis-pinane

Guidance literature:: With dihydrogen peroxide; (trans-1,2-diaminocyclohexane)methyltrioxorhenium; In dichloromethane; water; acetonitrile; at -10 ℃; for 1h;
DOI:10.1016/j.tet.2004.11.065