1-Azido-2-iodo-4-methylbenzene

Base Information

Chemical Name:1-Azido-2-iodo-4-methylbenzene
CAS No.:122099-10-9
Molecular Formula:C7H6IN3
Molecular Weight:259.049
Hs Code.:
DSSTox Substance ID:DTXSID40558131
Nikkaji Number:J1.730.887D
Wikidata:Q82440303

Synonyms:1-Azido-2-iodo-4-methylbenzene;122099-10-9;DTXSID40558131

Suppliers and Price of 1-Azido-2-iodo-4-methylbenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 1-Azido-2-iodo-4-methylbenzene

Chemical Property:

XLogP3:3.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:258.96064
Heavy Atom Count:11
Complexity:177

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=C(C=C1)N=[N+]=[N-])I

Technology Process of 1-Azido-2-iodo-4-methylbenzene

There total 3 articles about 1-Azido-2-iodo-4-methylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 29289-13-2
2-iodo-4-methylaniline

: 122099-10-9
1-azido-2-iodo-4-methyl-benzene

Guidance literature:: 2-iodo-4-methylaniline; With sulfuric acid; In water; Heating;

With sodium nitrite; In water; at 0 - 5 ℃; for 1h;

With sodium azide; In water; Petroleum ether; at 10 - 20 ℃; for 4h;
DOI:10.1039/c9ob00615j

Reference yield:

: 106-49-0,12221-03-3
p-toluidine

: 122099-10-9
1-azido-2-iodo-4-methyl-benzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydrogencarbonate; iodine / dichloromethane; water / 72 h / Schlenk technique; Inert atmosphere

2.1: sulfuric acid / water / Heating

2.2: 1 h / 0 - 5 °C

2.3: 4 h / 10 - 20 °C

With sulfuric acid; iodine; sodium hydrogencarbonate; In dichloromethane; water;
DOI:10.1039/c9ob00615j