29289-13-2

Basic information

• Product Name: 2-IODO-4-METHYLANILINE
• Synonyms: 2-IODO-4-METHYLANILINE;BUTTPARK 34\09-13;4-Amino-2-iodotoluene~3-Iodo-p-toluidine;4-Amino-3-iodotoluene;2-Iodo-4-methylbenzenamine;2-Iodo-4-Methylanline;2-Iodo-4-MethylphenylaMine;4-Amino-3-iodotoluene, 2-Iodo-p-toluidine
• CAS NO: 29289-13-2
• Molecular Formula: C₇H₈IN
• Molecular Weight: 233.05
• Product Categories: Anilines, Aromatic Amines and Nitro Compounds;Anilines, Amides & Amines;Iodine Compounds
• Mol File: 29289-13-2.mol
• Article Data: 70

Chemical Properties

• Melting Point: 34-37°C
• Boiling Point: 273°C (rough estimate)
• Flash Point: >110°C
• Appearance: /
• Density: 1.7004 (estimate)
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• PKA: 2.97±0.10(Predicted)
• CAS DataBase Reference: 2-IODO-4-METHYLANILINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-IODO-4-METHYLANILINE(29289-13-2)
• EPA Substance Registry System: 2-IODO-4-METHYLANILINE(29289-13-2)

Safety Data

• Hazard Codes: T,Xi
• Statements: 36/37/38-41-37/38-25
• Safety Statements: 26-37/39-36/37/39-27-45
• RIDADR: 2811
• WGK Germany: 3
• HazardClass: IRRITANT
• PackingGroup: Ⅲ
• Hazardous Substances Data: 29289-13-2(Hazardous Substances Data)

Usage

Chemical Properties

Milky white solid

Synthesis Reference(s)

Tetrahedron Letters, 30, p. 899, 1989 DOI: 10.1016/S0040-4039(00)95273-0

Upstream product

• 106-49-0 p-toluidine 
• 60-29-7 diethyl ether 
• 7732-18-5 water 
• 7553-56-2 iodine 
• 67-56-1 methanol 
• 540-23-8 p-toluidine hydrochloride 
• 52488-29-6 2-iodo-4-methyl-1-nitrobenzene 
• 496-72-0 4-methyl-1,2-diaminobenzene 
• 142-71-2 copper diacetate 
• 64-19-7 acetic acid 
• 784183-53-5 2,2,2-trifluoro-N-(2-iodo-4-methylphenyl)acetamide 
• 104-94-9 4-methoxy-aniline 
• 122099-10-9 1-azido-2-iodo-4-methyl-benzene 

Downstream Products

• 29289-16-5 N-(2-iodo-4-methylphenyl)acetamide 
• 64275-31-6 (2-iodo-4-methyl-phenyl)-urea 
• 180624-14-0 4-methyl-2-[2-(trimethylsilyl)ethynyl]aniline 
• 205756-33-8 N-(2-iodo-4-methylphenyl)pivalamide 
• 7553-56-2 iodine 
• 106-49-0 p-toluidine 
• 64662-57-3 2,6-diiodo-4-methylaniline 
• 10241-97-1 5-methylindole-2-carboxylic acid 
• 927896-38-6 (E)-1-(2-iodo-4-methylphenyl)-2-phenyldiazene 
• 835872-99-6 N-(2-iodo-4-methylphenyl)methylamine 

Relevant articles and documents

Design of a fused triazolyl 2-quinolinone unnatural nucleoside via tandem CuAAC-Ullmann coupling reaction and study of photophysical property

This report presents the design and synthesis of a novel fused triazolyl 2-quinolinone (FTQuon) nucleoside as a new generation of angularly widened unnatural nucleobase surrogate with two possible H-bonding faces-one H-bond acceptor and another donor. The

Ni-NiO heterojunctions: a versatile nanocatalyst for regioselective halogenation and oxidative esterification of aromatics

Herein, we report a facile method for the synthesis of Ni-NiO heterojunction nanoparticles, which we utilized for the nuclear halogenation reaction of phenol and substituted phenols usingN-bromosuccinimide (NBS). A remarkablepara-selectivity was achieved for the halogenated products under semi-aqueous conditions. Interestingly, blocking of thepara-position of phenol offeredortho-selective halogenation. In addition, the Ni-NiO nanoparticles catalyzed the oxidative esterification of carbonyl compounds with alcohol, diol or dithiol in the presence of a catalytic amount of NBS. It was observed that the aromatic carbonyls substituted with an electron-donating group favoured nuclear halogenation, whereas an electron-withdrawing group substitution in carbonyl compounds facilitated the oxidation reaction. In addition, the catalyst was magnetically separated and recycled 10 times. The tuned electronic structure at the Ni-NiO heterojunction controlled selectivity and activity as no suchpara-selectivity was observed with commercially available NiO or Ni nanoparticles.

A new 1,2,3-triazole-decorated imino-phenol: selective sensing of Zn2+, Cu2+and picric acid under different experimental conditions

A new 1,2,3-triazole-decorated imino-phenol1has been synthesized, characterized and employed in metal ion sensing. Compound1is weakly fluorescent in CH3CN-H2O (3?:?1, v/v, pH = 6.8, and 10 mM HEPES buffer containing 1% DMSO) and show