Silane, [1-(bromomethyl)ethenyl]dimethylphenyl-

Base Information

Chemical Name:Silane, [1-(bromomethyl)ethenyl]dimethylphenyl-
CAS No.:122244-65-9
Molecular Formula:C11H15BrSi
Molecular Weight:255.23
Hs Code.:
DSSTox Substance ID:DTXSID60445796
Wikidata:Q82264324
Mol file:122244-65-9.mol

Synonyms:Silane, [1-(bromomethyl)ethenyl]dimethylphenyl-;122244-65-9;DTXSID60445796

Suppliers and Price of Silane, [1-(bromomethyl)ethenyl]dimethylphenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of Silane, [1-(bromomethyl)ethenyl]dimethylphenyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:254.01264
Heavy Atom Count:13
Complexity:181

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C1=CC=CC=C1)C(=C)CBr

Technology Process of Silane, [1-(bromomethyl)ethenyl]dimethylphenyl-

There total 4 articles about Silane, [1-(bromomethyl)ethenyl]dimethylphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 101844-22-8
2-(dimethyl(phenyl)silyl)prop-2-en-1-ol

: 122244-65-9
2-(phenyldimethylsilyl)-prop-2-en-1-yl bromide

Guidance literature:: With bromine; triethylamine; triphenylphosphine; In dichloromethane; at -20 ℃; for 0.166667h;
DOI:10.1021/jo0056343

Reference yield: 66.0%

: 128-08-5
N-Bromosuccinimide

: 91076-17-4
dimethyl(phenyl)(prop-1-en-2-yl)silane

: 122244-65-9
2-(phenyldimethylsilyl)-prop-2-en-1-yl bromide

Guidance literature:: With dibenzoyl peroxide; In tetrachloromethane; for 12h; Heating;
DOI:10.1016/0040-4020(89)80069-9

Reference yield:

: 17156-64-8
(dimethylphenylsilyl)acetylene

: 122244-65-9
2-(phenyldimethylsilyl)-prop-2-en-1-yl bromide

Guidance literature:: Multi-step reaction with 2 steps

1.1: DIBAL / diethyl ether / 1 h / Heating

1.2: MeLi / tetrahydrofuran; diethyl ether / 0 - 20 °C

1.3: 71 percent / tetrahydrofuran; diethyl ether / 14 h / 20 °C

2.1: 89 percent / Br₂; triphenylphosphine; triethylamine / CH₂Cl₂ / 0.17 h / -20 °C

With bromine; diisobutylaluminium hydride; triethylamine; triphenylphosphine; In diethyl ether; dichloromethane;
DOI:10.1021/jo0056343