Butanedioic acid, oxophenyl-, di-2-propenyl ester

Base Information

• Chemical Name: Butanedioic acid, oxophenyl-, di-2-propenyl ester
• CAS No.: 125582-93-6
• Molecular Formula: C16H16O5
• Molecular Weight: 288.3
• Mol file: 125582-93-6.mol

Synonyms:

Chemical Property of Butanedioic acid, oxophenyl-, di-2-propenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Butanedioic acid, oxophenyl-, di-2-propenyl ester

There total 1 articles about Butanedioic acid, oxophenyl-, di-2-propenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

diallyl oxalate (615-99-6) + allyl phenylacetate (1797-74-6) → allyl 3-allyloxycarbonyl-2-oxo-3-phenylpropanoate (125582-93-6)

Guidance literature:

With sodium hydride; allyl alcohol; In tetrahydrofuran; for 4h; Ambient temperature;

DOI:10.1016/0022-328X(94)80126-6

Reference yield: 73.0%

allyl 3-allyloxycarbonyl-2-oxo-3-phenylpropanoate (125582-93-6) → phenyllactic acid (828-01-3)

Guidance literature:

With formic acid; Ru₂(cod)2(OCOCF₃)4-1,4-bis(diphenylphosphino)butane; triethylamine; 1,4-di(diphenylphosphino)-butane; In 1,4-dioxane; for 4h; Heating;

DOI:10.1246/cl.1992.1365

Reference yield: 64.0%

allyl 3-allyloxycarbonyl-2-oxo-3-phenylpropanoate (125582-93-6) → 2-oxo-3-(phenyl)propionic acid (156-06-9)

Guidance literature:

With formic acid; triethylamine; triphenylphosphine; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In 1,4-dioxane; Ambient temperature;

upstream raw materials:

diallyl oxalate

allyl phenylacetate

Downstream raw materials:

2-oxo-3-(phenyl)propionic acid

phenyllactic acid

Refernces

• 1、 Shimizu, Isao,Makuta, Toshiyuki,Oshima, Masato. "Facile Synthesis of α-Keto Acids and Esters by Palladium-Catalyzed Decarboxylation Reactions of Diallyl α-Oxalcarboxylates". . p. 1457 - 1460. Retrieved 2007/10/02.