615-99-6

Basic information

• Product Name: DIALLYL OXALATE
• Synonyms: ethanedioicacid,di-2-propenylester;Oxalic acid, diallyl ester;DIALLYL OXALATE;diprop-2-enyl ethanedioate;diprop-2-enyl oxalate;(COOCH2CH=CH2)2;Ethanedioic acid, di-2-propenyl ester
• CAS NO: 615-99-6
• Molecular Formula: C₈H₁₀O₄
• Molecular Weight: 170.16
• EINECS: 210-458-5
• Product Categories: monomer
• Mol File: 615-99-6.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 85-86°C 3mm
• Flash Point: 86.6°C
• Appearance: /
• Density: 1.1582
• Vapor Pressure: 0.131mmHg at 25°C
• Refractive Index: 1.4481 (estimate)
• CAS DataBase Reference: DIALLYL OXALATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIALLYL OXALATE(615-99-6)
• EPA Substance Registry System: DIALLYL OXALATE(615-99-6)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 615-99-6(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron, 49, p. 2629, 1993 DOI: 10.1016/S0040-4020(01)86342-0

InChI:InChI=1/C8H10O4/c1-3-5-11-7(9)8(10)12-6-4-2/h3-4H,1-2,5-6H2

Upstream product

• 144-62-7 oxalic acid 
• 107-18-6 allyl alcohol 
• 148705-17-3 diisopropenyl oxalate 
• 79-37-8 oxalyl dichloride 
• 513-42-8 3-hydroxy-2-methyl-1-propene 
• 2215-04-5 dimethoxysuccinate de methyle 
• 40227-15-4 N,N'-diacetyl-oxalamide 
• 556-56-9 allyl iodid 

Downstream Products

• 125582-93-6 allyl 3-allyloxycarbonyl-2-oxo-3-phenylpropanoate 
• 125582-89-0 allyl 3-allyloxycarbonyl-2-oxo-4-phenylbutanoate 
• 115-07-1 allyl radical 
• 15022-08-9 diallylcarbonate 
• 1214260-77-1 allyl (Z)-2-allyloxy-3-(4-methoxyphenyl)acrylate 
• 1367075-21-5 allyl 2-cyclohexyl-2-oxoacetate 
• 1367075-16-8 allyl 2-(4-fluorophenyl)-2-oxoacetate 
• 1367075-20-4 allyl 2-(4-methoxyphenyl)-2-oxoacetate 
• 62936-34-9 allyl 2-oxo-2-phenylacetate 
• 1360924-09-9 allyl 2-(4-chlorophenyl)-2-oxoacetate 
• 1367075-15-7 allyl 2-(3-fluorophenyl)-2-oxoacetate 
• 1367075-18-0 allyl 2-(3-methoxyphenyl)-2-oxoacetate 
• 1367074-90-5 allyl 2-(4-methoxyphenylimino)-2-(4-chlorophenyl)acetate 
• 1367074-89-2 allyl 2-(4-methoxyphenylimino)-2-(4-fluorophenyl)acetate 

Relevant articles and documents

Synthesis of γ,δ-unsaturated quaternary α-alkylamino acids using umpolung reaction and Claisen rearrangement

A new synthesis of γ,δ-unsaturated quaternary α-amino acid derivatives was developed utilizing N-alkylation and Claisen rearrangement of allyl α-iminocarboxylates.

New stereospecific synthesis of Tesaglitazar and Navaglitazar precursors

A new synthetic route of to pharmaceutical intermediates (S)-1a-b and (S)-14 is reported. The reaction pathway is based on the baker's yeast-mediated reduction of the α-alkoxy cinnamaldehydes 9a-c to give the corresponding (S)-alcohols in good yields and

Method of preparation of oxalic acid esters and amides

A new process is described for the preparation of oxalic acid esters and amides of general formula (I) STR1 wherein Z designates an --OR or --NR1 R2 group, wherein R represents substituted or unsubstituted alkyl, alkenyl, cycloalkyl, aryl, or aryl-alkyl, R1 is hydrogen or substituted or unsubstituted alkyl, alkenyl, cycloalkyl, aryl, or aryl-alkyl, R2 represents substituted or unsubstituted alkyl, alkenyl, cycloalkyl, aryl, or aryl-alkyl, or R1 and R2 taken together with the adjacent nitrogen atom represent a saturated 5-, 6-, 7-, or 8-membered heterocyclic ring, which may contain an additional heteroatom selected from --O--, --S--, and --N(H, Alkyl)--, and optionally bear one or more alkyl or alkenyl substituents, and Z1 designates an --OR or --NR1 R2 group, wherein R, R1, and R2 are as defined before, or a group --NHCOCH3, which comprises the base-catalysed reaction of diacetyloxamide with an alcohol ROH or/and an amine HNR1 R2. The compounds of formula (I) have many industrial utilities, mainly as intermediates and stabilizers in the polymer field.