1,1-Cyclopropanedicarboxylic acid, 2-(4-chlorophenyl)-, dimethyl ester, (R)-

Base Information

Chemical Name:1,1-Cyclopropanedicarboxylic acid, 2-(4-chlorophenyl)-, dimethyl ester, (R)-
CAS No.:127604-92-6
Molecular Formula:C13H13ClO4
Molecular Weight:268.697
Hs Code.:

Synonyms:

Suppliers and Price of 1,1-Cyclopropanedicarboxylic acid, 2-(4-chlorophenyl)-, dimethyl ester, (R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of 1,1-Cyclopropanedicarboxylic acid, 2-(4-chlorophenyl)-, dimethyl ester, (R)-

Chemical Property:

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1,1-Cyclopropanedicarboxylic acid, 2-(4-chlorophenyl)-, dimethyl ester, (R)-

There total 19 articles about 1,1-Cyclopropanedicarboxylic acid, 2-(4-chlorophenyl)-, dimethyl ester, (R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1073-67-2,24991-47-7
4-vinylbenzyl chloride

: 6773-29-1
dimethyl diazomalonate

: 127604-92-6,132145-65-4
dimethyl 2-(4-chlorophenyl)cyclopropane-1,1-dicarboxylate

Guidance literature:: 4-vinylbenzyl chloride; With bis[rhodium(α,α,α',α'-tetramethyl-1,3-benzenedipropionic acid)]; In dichloromethane; at 0 ℃; for 0.0833333h; Inert atmosphere;

dimethyl diazomalonate; In dichloromethane; at 0 - 23 ℃; Inert atmosphere;
DOI:10.1002/chem.201102583

Reference yield: 93.0%

: 1073-67-2,24991-47-7
4-vinylbenzyl chloride

: 1379474-24-4
dimethyl 2-((2-methoxyphenyl)-λ³-iodanylidene)malonate

: 127604-92-6,132145-65-4
dimethyl 2-(4-chlorophenyl)cyclopropane-1,1-dicarboxylate

Guidance literature:: With dirhodium tetraacetate; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/ol301268j

Reference yield: 74.0%

: 1073-67-2,24991-47-7
4-vinylbenzyl chloride

: 868-26-8
dimethyl 2-bromomalonate

: 127604-92-6,132145-65-4
dimethyl 2-(4-chlorophenyl)cyclopropane-1,1-dicarboxylate

Guidance literature:: With N,N,N',N'',N'''-pentamethyldiethylenetriamine; CuH₁₂O₆⁽²⁺⁾*2BF₄^(1-); In toluene; at 20 ℃; for 20h; Inert atmosphere;
DOI:10.1039/c5cc04697a