1379474-24-4

Basic information

• Product Name: dimethyl 2-((2-methoxyphenyl)-λ³-iodanylidene)malonate
• Synonyms: dimethyl 2-((2-methoxyphenyl)-λ³-iodanylidene)malonate
• CAS NO: 1379474-24-4
• Molecular Weight: 364.137
• Mol File: 1379474-24-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: dimethyl 2-((2-methoxyphenyl)-λ³-iodanylidene)malonate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 2-((2-methoxyphenyl)-λ³-iodanylidene)malonate(1379474-24-4)
• EPA Substance Registry System: dimethyl 2-((2-methoxyphenyl)-λ³-iodanylidene)malonate(1379474-24-4)

Safety Data

• Hazardous Substances Data: 1379474-24-4(Hazardous Substances Data)

Upstream product

• 533-58-4 2-Iodophenol 
• 69180-49-0 1-diacetoxy-2-methoxyphenyl-λ³-iodane 
• 108-59-8 malonic acid dimethyl ester 
• 529-28-2 4-iodoanisol 

Downstream Products

• 83759-89-1 2-pyridinium bis(methoxycarbonyl)methylide 
• 3709-20-4 dimethyl 2-phenyl-1,1-cyclopropanedicarboxylate 
• 17870-64-3 quinolinium bis(methoxycarbonyl)methylide 
• 127604-92-6 dimethyl 2-(4-chlorophenyl)cyclopropane-1,1-dicarboxylate 
• 75073-97-1 dimethyl 2-(4-methoxyphenyl)cyclopropane-1,1-dicarboxylate 
• 132145-64-3 dimethyl 2-(p-methylphenyl)cyclopropane-1,1-dicarboxylate 
• 1379474-28-8 dimethyl 2-(3-methylphenyl)cyclopropane-1,1-dicarboxylate 
• 38323-08-9 dimethyl (2RS,3SR)-2-methyl-3-phenylcyclopropane-1,1-dicarboxylate 
• 904294-15-1 2‐(4-fluorophenyl)cyclopropane-1,1-dicarboxylic acid dimethyl ester 
• 851293-09-9 dimethyl 2-(4-bromophenyl)cyclopropane-1,1-dicarboxylate 
• 38323-08-9 dimethyl (2SR,3SR)-2-methyl-3-phenylcyclopropane-1,1-dicarboxylate 
• 24420-59-5 methyl phenyl sulfonium bismethoxycarbonylmethylide 
• 24420-61-9 diphenylsulfoxonium bis(methoxycarbonyl)methylide 
• 1110700-55-4 dimethyl 2-(2-bromophenyl)cyclopropane-1,1-dicarboxylate 

Relevant articles and documents

Blue LED Irradiation of Iodonium Ylides Gives Diradical Intermediates for Efficient Metal-free Cyclopropanation with Alkenes

A facile and highly chemoselective synthesis of doubly activated cyclopropanes is reported where mixtures of alkenes and β-dicarbonyl-derived iodonium ylides are irradiated with light from blue LEDs. This metal-free synthesis gives cyclopropanes in yields

Design, preparation, X-ray crystal structure, and reactivity of o-alkoxyphenyliodonium bis(methoxycarbonyl)methanide, a highly soluble carbene precursor

The preparation, X-ray structure, and reactivity of new, highly soluble, and reactive iodonium ylides derived from malonate methyl ester and bearing an ortho substituent on the phenyl ring are reported. These new reagents show higher reactivity than common phenyliodonium ylides in the Rh-catalyzed cyclopropanation, C-H insertion, and transylidation reactions under homogeneous conditions.