1-Cyclohexene-1-carboxylic acid, 4-(1,5-dimethyl-3-oxo-4-hexenyl)-, methyl ester

Base Information

Chemical Name:1-Cyclohexene-1-carboxylic acid, 4-(1,5-dimethyl-3-oxo-4-hexenyl)-, methyl ester
CAS No.:13123-83-6
Molecular Formula:C₁₆H₂₄O₃
Molecular Weight:264.365
Hs Code.:

Synonyms:

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Chemical Property of 1-Cyclohexene-1-carboxylic acid, 4-(1,5-dimethyl-3-oxo-4-hexenyl)-, methyl ester

Chemical Property:

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Technology Process of 1-Cyclohexene-1-carboxylic acid, 4-(1,5-dimethyl-3-oxo-4-hexenyl)-, methyl ester

There total 11 articles about 1-Cyclohexene-1-carboxylic acid, 4-(1,5-dimethyl-3-oxo-4-hexenyl)-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 63579-89-5
triethyl pentane-1,3,5-tricarboxylate

: 13123-83-6
dehydrojuvabione

Guidance literature:: Multi-step reaction with 9 steps

1: 1.) Na, 2.) H₃O⁽¹⁺⁾, 3.) H⁽¹⁺⁾ / 1.) toluene, 3.) C₆H₆

2: 1.) H⁽¹⁺⁾, 2.) LiAlH₄ / 1.) C₆H₆, 2.) THF, 3.) Collins, CH₂Cl₂

3: 94 percent

4: 92 percent / Al₂O₃ / tetrahydrofuran / 10 h / 40 °C

5: 91 percent / diethyl ether / 0 °C

6: 97 percent / aq. H₂SO₄ / tetrahydrofuran / Heating

7: aq. AcOH, EtOH / 0 °C

8: 92 percent / POCl₃, py / 1.) room temperature, 3 h, 2.) reflux, 10 min

9: 1.) gas HCl, 2.) DABCO / 1,) reflux, 12 h, 2.) reflux, 12 h

With pyridine; 1,4-diaza-bicyclo[2.2.2]octane; hydrogenchloride; aluminum oxide; lithium aluminium tetrahydride; ethanol; sulfuric acid; oxonium; sodium; hydrogen cation; acetic acid; trichlorophosphate; In tetrahydrofuran; diethyl ether;

Reference yield:

: 17159-79-4
ethyl 4-oxocyclohexane-1-carboxylate

: 13123-83-6
dehydrojuvabione

Guidance literature:: Multi-step reaction with 8 steps

1: 1.) H⁽¹⁺⁾, 2.) LiAlH₄ / 1.) C₆H₆, 2.) THF, 3.) Collins, CH₂Cl₂

2: 94 percent

3: 92 percent / Al₂O₃ / tetrahydrofuran / 10 h / 40 °C

4: 91 percent / diethyl ether / 0 °C

5: 97 percent / aq. H₂SO₄ / tetrahydrofuran / Heating

6: aq. AcOH, EtOH / 0 °C

7: 92 percent / POCl₃, py / 1.) room temperature, 3 h, 2.) reflux, 10 min

8: 1.) gas HCl, 2.) DABCO / 1,) reflux, 12 h, 2.) reflux, 12 h

With pyridine; 1,4-diaza-bicyclo[2.2.2]octane; hydrogenchloride; aluminum oxide; lithium aluminium tetrahydride; ethanol; sulfuric acid; hydrogen cation; acetic acid; trichlorophosphate; In tetrahydrofuran; diethyl ether;

Reference yield:

: 93245-98-8
1,4-dioxaspiro[4.5]decane-8-carbaldehyde

: 13123-83-6
dehydrojuvabione

Guidance literature:: Multi-step reaction with 7 steps

1: 94 percent

2: 92 percent / Al₂O₃ / tetrahydrofuran / 10 h / 40 °C

3: 91 percent / diethyl ether / 0 °C

4: 97 percent / aq. H₂SO₄ / tetrahydrofuran / Heating

5: aq. AcOH, EtOH / 0 °C

6: 92 percent / POCl₃, py / 1.) room temperature, 3 h, 2.) reflux, 10 min

7: 1.) gas HCl, 2.) DABCO / 1,) reflux, 12 h, 2.) reflux, 12 h

With pyridine; 1,4-diaza-bicyclo[2.2.2]octane; hydrogenchloride; aluminum oxide; ethanol; sulfuric acid; acetic acid; trichlorophosphate; In tetrahydrofuran; diethyl ether;