63579-89-5

Usage

Uses

Used in Flavor and Fragrance Industry:
Triethyl pentane-1,3,5-tricarboxylate is utilized as a flavoring agent, imparting a fruity, rum-like aroma to food products. Its unique scent profile also makes it suitable for the production of fragrances and perfumes, where it contributes to the creation of complex and appealing scents.
Used in Food Industry:
In the food industry, triethyl pentane-1,3,5-tricarboxylate is used as an additive to enhance the flavor of various products. Its fruity and rum-like aroma adds depth and complexity to the taste, making it a valuable ingredient in the development of new and innovative food items.
Used in Perfumery:
Triethyl pentane-1,3,5-tricarboxylate is employed in the creation of perfumes, where it serves as a key component in the formulation of unique and captivating fragrances. Its ability to provide a slightly sweet and fruity scent makes it an essential ingredient in the perfumer's palette.

InChI:InChI=1/C14H24O6/c1-4-18-12(15)9-7-11(14(17)20-6-3)8-10-13(16)19-5-2/h11H,4-10H2,1-3H3

Upstream product

• 63579-82-8 2,2,4-Trichloro-4-ethoxycarbonyl-heptanedioic acid diethyl ester 
• 64-17-5 ethanol 
• 6940-58-5 pentane-1,3,5-tricarboxylic acid 
• 5621-43-2 diethyl 2-methyleneglutarate 
• 1444-05-9 diethyl 2,2-bis(2-cyanoethyl)malonate 
• 107-13-1 acrylonitrile 
• 105-53-3 diethyl malonate 

Downstream Products

• 58660-59-6 Diethyl cyclohexanone-2,4-dicarboxylic ester 
• 17159-79-4 ethyl 4-oxocyclohexane-1-carboxylate 
• 93246-05-0 2-(4-Oxo-cyclohexyl)-6-methyl-heptanon-⁽⁴⁾ 
• 13123-83-6 dehydrojuvabione 
• 93245-98-8 1,4-dioxaspiro[4.5]decane-8-carbaldehyde 
• 93246-06-1 4-(1,5-Dimethyl-3-oxo-hex-4-enyl)-cyclohexanone 
• 93246-08-3 4-(1,5-Dimethyl-3-oxo-hex-4-enyl)-cyclohex-1-enecarbonitrile 
• 93246-07-2 4-(1,5-Dimethyl-3-oxo-hex-4-enyl)-1-hydroxy-cyclohexanecarbonitrile 
• 1489-97-0 ethyl 1,4-dioxaspiro[4.5]decane-8-carboxylate 
• 874-61-3 4-oxocyclohexanecarboxylic acid 
• 58660-74-5 diethyl 4-aminocyclohexane-1,3-dicarboxylate 
• 1312919-90-6 4-(6-(4-cyano-2-fluorobenzyloxy)naphthalene-2-sulfonamido)cyclohexane-1,3-dicarboxylic acid 
• 1312919-81-5 4-(6-butoxynaphthalene-2-sulfonamido)cyclohexane-1,3-dicarboxylic acid 
• 1312919-72-4 diethyl 4-(6-(4-cyano-2-fluorobenzyloxy)naphthalene-2-sulfonamido)cyclohexane-1,3-dicarboxylate 

Relevant academic research and scientific papers

Stereoselective synthesis of alicyclic ketones: A hydrogen borrowing approach

A highly diastereoselective annulation strategy for the synthesis of alicyclic ketones from diols and pentamethylacetophenone is described. This process is mediated by a commercially available iridium(III) catalyst, and provides efficient access to a wide range of cyclopentane and cyclohexane products with high levels of stereoselectivity. The origins of diastereoselectivity in the annulation reaction have been explored by a series of control experiments, which provides an explanation for how each stereocentre around the newly forged ring is controlled.

Stereoselective Synthesis of Cyclohexanes via an Iridium Catalyzed (5 + 1) Annulation Strategy

An iridium catalyzed method for the synthesis of functionalized cyclohexanes from methyl ketones and 1,5-diols is described. This process operates by two sequential hydrogen borrowing reactions, providing direct access to multisubstituted cyclic products with high levels of stereocontrol. This methodology represents a novel (5 + 1) strategy for the stereoselective construction of the cyclohexane core.

Synthesis and conformation studies of a dodecaazanonacyclotetratetracontane

Compound 3 was prepared by self-assembly of 1,3,5-pentanetriamine and aqueous formaldehyde in quantitative yield (Figure 1). This molecule can exist in four well-defined diamond-lattice conformations of symmetries D(2d), S4, C(2v) and D(2d). Low-temperature 13C NMR spectroscopy indicates the existence of three main conformers; their relative populations depend on the solvent used. An extra set of low- intensity lines is also observed. A conformation interconversion scheme is proposed; it involves two additional less populated quasi-diamond-lattice intermediates derived from a helix compressed along its axis. One of these is trapped as a 1:2 clathrate with 1,4-dioxane; its crystal structure is reported.

FURTHER EXTENSIONS OF THE KINETIC ENOLATE METHOD FOR TERPENOID SYNTHESES

New stereorandom syntheses of juvabione and dehydrojuvabione using kinetic enolates as synthons are described.

Synthetic Studies in Carbocyclic Systems : Part I - A new Synthesis of Nopinone

Base-induced intramolecular nucleophilic displacement of the tosyloxy group of 4-isopropyl-7-tosyloxycyclohexanone affords nopinone , identical with an authentic specimen.