Ethyl 3-oxo-4-[(prop-2-en-1-yl)oxy]butanoate

Base Information

Chemical Name:Ethyl 3-oxo-4-[(prop-2-en-1-yl)oxy]butanoate
CAS No.:134989-37-0
Molecular Formula:C9H14O4
Molecular Weight:186.208
Hs Code.:
DSSTox Substance ID:DTXSID70577517
Nikkaji Number:J1.510.408B
Wikidata:Q82467550
Mol file:134989-37-0.mol

Synonyms:134989-37-0;Ethyl 3-oxo-4-[(prop-2-en-1-yl)oxy]butanoate;DTXSID70577517;AKOS013207283

Suppliers and Price of Ethyl 3-oxo-4-[(prop-2-en-1-yl)oxy]butanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Ethyl 3-oxo-4-[(prop-2-en-1-yl)oxy]butanoate

Chemical Property:

XLogP3:0.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:8
Exact Mass:186.08920892
Heavy Atom Count:13
Complexity:186

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCOC(=O)CC(=O)COCC=C

Technology Process of Ethyl 3-oxo-4-[(prop-2-en-1-yl)oxy]butanoate

There total 1 articles about Ethyl 3-oxo-4-[(prop-2-en-1-yl)oxy]butanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 623-73-4
diazoacetic acid ethyl ester

: 55207-76-6
2-(allyloxy)acetaldehyde

: 134989-37-0
ethyl 4-allyloxy-3-oxobutanoate

Guidance literature:: diazoacetic acid ethyl ester; With tin(ll) chloride; In dichloromethane; at 20 ℃; for 0.25h;

2-(allyloxy)acetaldehyde; In dichloromethane; at -10 - 20 ℃;
DOI:10.1021/ol049493t

Reference yield: 100.0%

: 3886-69-9
(R)-1-phenyl-ethyl-amine

: 134989-37-0
ethyl 4-allyloxy-3-oxobutanoate

: 565170-41-4
(Z)-4-Allyloxy-3-((R)-1-phenyl-ethylamino)-but-2-enoic acid ethyl ester

Guidance literature:: With acetic acid; In tetrahydrofuran; at 60 ℃;
DOI:10.1055/s-2003-38362

Reference yield:

: 134989-37-0
ethyl 4-allyloxy-3-oxobutanoate

: 693273-97-1
5-allyloxy-4-benzyloxy-1-diazopentan-2-one

Guidance literature:: Multi-step reaction with 5 steps

1: 80 percent / NaBH₄ / ethanol / 0.17 h / -10 °C

2: 97 percent / Ag₂O; CaSO₄ / benzene / 12 h

3: aq. LiOH / methanol / 3 h

4: Et₃N / diethyl ether / 4 h / -10 °C

5: 200 mg / diethyl ether / 0 °C

With calcium sulfate; lithium hydroxide; sodium tetrahydroborate; triethylamine; silver(l) oxide; In methanol; diethyl ether; ethanol; benzene;
DOI:10.1021/ol049493t