4'-IODO-4-DIMETHYLAMINOAZOBENZENE

Base Information

• Chemical Name: 4'-IODO-4-DIMETHYLAMINOAZOBENZENE
• CAS No.: 3805-67-2
• Molecular Formula: C14H14 I N3
• Molecular Weight: 351.19
• Hs Code.: 2927000090
• Mol file: 3805-67-2.mol

Synonyms:Aniline,p-[(p-iodophenyl)azo]-N,N-dimethyl- (7CI,8CI); Benzenamine,4-[(4-iodophenyl)azo]-N,N-dimethyl- (9CI); 4-(Dimethylamino)-4'-iodoazobenzene;4'-Iodo-4-dimethylaminoazobenzene; 4'-Iodo-N,N-dimethyl-4-aminoazobenzene

Chemical Property of 4'-IODO-4-DIMETHYLAMINOAZOBENZENE

Chemical Property:

• Vapor Pressure: 7.1E-08mmHg at 25°C
• Melting Point: 162°C
• Boiling Point: 438.1°Cat760mmHg
• Flash Point: 218.7°C
• PSA: 27.96000
• Density: 1.48g/cm³
• LogP: 4.77260

Purity/Quality:

97% ^*data from raw suppliers

4'-Iodo-4-dimethylaminoazobenzene >97.0%(T) ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4'-IODO-4-DIMETHYLAMINOAZOBENZENE

There total 1 articles about 4'-IODO-4-DIMETHYLAMINOAZOBENZENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-Iodo-benzenediazonium (19262-76-1) + sodium acetate (127-09-3) → 4-(dimethylamino)-4'-iodoazobenzene (3805-67-2)

Guidance literature:

anschliessend mit N,N-Dimethyl-anilin in Essigsaeure;

DOI:10.1021/ja01156a092

Reference yield: 89.0%

N,N-diethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline (91011-76-6) + 4-(dimethylamino)-4'-iodoazobenzene (3805-67-2) → C24H28N4

Guidance literature:

With potassium phosphate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri tert-butylphosphoniumtetrafluoroborate; In 1,4-dioxane; at 100 ℃; for 18h; Inert atmosphere;

Reference yield: 79.0%

4-(dimethylamino)-4'-iodoazobenzene (3805-67-2) + 2-ethynyl-5,5,10,10,15,15,20,20-octamethylcalix[4]pyrrole (265137-02-8) → 2-[(4-{[4-(dimethylamino)phenyl]azo}phenyl)ethynyl]-5,5,10,10,15,15,20,20-octamethylcalix[4]pyrrole

Guidance literature:

copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾;

DOI:10.1016/S0040-4039(99)02295-9

upstream raw materials:

4-Iodo-benzenediazonium

sodium acetate

Downstream raw materials:

4-amino-N,N-dimethylaniline

p-aminoiodobenzene