[(Phenylphosphanediyl)di(ethane-2,1-diyl)]bis(dicyclohexylphosphane)

Base Information

Chemical Name:[(Phenylphosphanediyl)di(ethane-2,1-diyl)]bis(dicyclohexylphosphane)
CAS No.:136667-81-7
Molecular Formula:C34H57P3
Molecular Weight:558.748
Hs Code.:
DSSTox Substance ID:DTXSID80510910
Nikkaji Number:J2.332.473C
Wikidata:Q82369464

Synonyms:136667-81-7;DTXSID80510910;[(Phenylphosphanediyl)di(ethane-2,1-diyl)]bis(dicyclohexylphosphane)

Suppliers and Price of [(Phenylphosphanediyl)di(ethane-2,1-diyl)]bis(dicyclohexylphosphane)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of [(Phenylphosphanediyl)di(ethane-2,1-diyl)]bis(dicyclohexylphosphane)

Chemical Property:

XLogP3:8.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:11
Exact Mass:558.36731281
Heavy Atom Count:37
Complexity:512

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCC(CC1)P(CCP(CCP(C2CCCCC2)C3CCCCC3)C4=CC=CC=C4)C5CCCCC5

Technology Process of [(Phenylphosphanediyl)di(ethane-2,1-diyl)]bis(dicyclohexylphosphane)

There total 1 articles about [(Phenylphosphanediyl)di(ethane-2,1-diyl)]bis(dicyclohexylphosphane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 26681-88-9
divinylphenylphosphine

: 829-84-5
dicyclohexylphosphane

: 136667-81-7
bis<(dicyclohexylphosphino)ethyl>phenylphosphine

Guidance literature:: With 2,2'-azobis(isobutyronitrile); for 48h; Irradiation;

Reference yield: 96.0%

: iron(II) chloride*1.5THF

: 136667-81-7
bis<(dicyclohexylphosphino)ethyl>phenylphosphine

: C₃₄H₅₇Cl₂FeP₃

Guidance literature:: In tetrahydrofuran; at 20 ℃; Schlenk technique; Inert atmosphere;
DOI:10.1002/anie.201711130

Reference yield: 95.0%

: 13985-78-9
tetraethylammonium hexacarbonylvanadium(-1)

: 136667-81-7
bis<(dicyclohexylphosphino)ethyl>phenylphosphine

: cis-[Et₄N][V(CO)4P(C₆H₁₁)2CH₂CH₂P(C₆H₅)CH₂CH₂P(C₆H₁₁)2]

Guidance literature:: In tetrahydrofuran; Irradiation (UV/VIS); irradiation for 60 min, N2 atm., ligand/complex molar ratio 1/1; concn., pptn. with n-heptane, stirring for 1 day for solidification of pasti product, filtration, washing with THF/heptane 1/3, drying in vac. for 6 h; elem. anal.;
DOI:10.1016/S0022-328X(00)82436-5