26681-88-9

Basic information

• Product Name: DIVINYLPHENYLPHOSPHINE
• Synonyms: DIVINYLPHENYLPHOSPHINE;phenyldivinylphosphine;Diethenylphenylphosphine;Divinylphenylphosphin
• CAS NO: 26681-88-9
• Molecular Formula: C₁₀H₁₁P
• Molecular Weight: 162.17
• EINECS: 247-900-1
• Product Categories: Catalysis and Inorganic Chemistry;Phosphorus Compounds;Phosphorus Precursors
• Mol File: 26681-88-9.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 55 °C0.05 mm Hg(lit.)
• Flash Point: 210 °F
• Appearance: /
• Density: 0.979 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.308mmHg at 25°C
• Refractive Index: n20/D 1.582(lit.)
• CAS DataBase Reference: DIVINYLPHENYLPHOSPHINE(CAS DataBase Reference)
• NIST Chemistry Reference: DIVINYLPHENYLPHOSPHINE(26681-88-9)
• EPA Substance Registry System: DIVINYLPHENYLPHOSPHINE(26681-88-9)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 26681-88-9(Hazardous Substances Data)

Usage

Uses

Reactant for:Synthesis of P-chiral phosphines via chiral metal template promoted asymmetric furan Diels-Alder reaction

InChI:InChI=1/C10H11P/c1-3-11(4-2)10-8-6-5-7-9-10/h3-9H,1-2H2

Upstream product

• 1826-67-1 vinyl magnesium bromide 
• 644-97-3 Dichlorophenylphosphine 
• 1638-86-4 diethyl phenylphosphonite 
• 79919-73-6 (OC)5WPPh(CH=CH₂)2 
• 18399-62-7 W(CO)5(PPh2H) 
• 829-85-6 diphenylphosphane 

Downstream Products

• 201612-04-6 Ru₃(CO)10(P(C₆H₅)(CHCH₂)2)2 
• 207689-31-4 Mo(CO)3(HN(CH₂CH₂PH₂)2)(P(CHCH₂)2C₆H₅) 
• 207689-32-5 Mo(CO)3(CH₃(CH₂)3N(CH₂CH₂PH₂)2)(P(CHCH₂)2C₆H₅) 
• 121935-47-5 bromo{phenylbis(5,6-dimethyl-7-phenyl-7-phosphabicyclo{2.2.1}hept-5-en-2-yl)phosphine}nickel(II) bromide-dichloromethane 
• 121935-48-6 bromobis{(2-vinylphenylphosphino)-5,6-dimethyl-7-phenyl-7-phosphabicyclo{2.2.1}hept-5-ene}nickel(II) bromide 
• 121935-50-0 dibromobis{2-(diphenylphosphino)-5,6-dimethyl-7-phenyl-7-phosphabicyclo{2.2.1}hept-5-ene}nickel(II) bromide-1.5-dichloromethane 
• 121935-37-3 dibromo{2-(diphenylphosphino)-5,6-dimethyl-7-phenyl-7-phosphabicyclo{2.2.1}hept-5-ene}nickel(II) 
• 1360110-14-0 bis(2-di(tert-butyl)phosphinoethyl)phenylphosphine 
• 1615244-31-9 C₃₈H₂₉F₁₂P₃ 
• 1615244-34-2 {[(4-CF₃-C₆H₄)₂PCH₂CH₂]₂PPh}MoCl₃ 
• 1615244-32-0 C₆₆H₉₇P₃ 
• 122170-86-9 cis-(Vy₂PhP)2platinum(II)I₂ 
• 102538-60-3 cis-(Vy₂PhP)2platinum(II)Br₂ 
• 124850-89-1 {(CH₃)2Sn(CH₂CH₂)2P(CH₃)C₆H₅}⁽¹⁺⁾*I^(1-)={(CH₃)2Sn(CH₂CH₂)2P(CH₃)C₆H₅}I 

Relevant articles and documents

New superhindered polydentate polyphosphine ligands P(CH2CH 2PtBu2)3, PhP(CH2CH 2PtBu2)2, P(CH2CH 2CH2PtBu2)3, and their ruthenium(II) chloride complexes

The synthesis and characterization of the extremely hindered phosphine ligands, P(CH2CH2PtBu2)3 (P2P3tBu, 1), PhP(CH2CH 2PtBu2)2 (PhP2P 2tBu, 2), and P(CH2CH2CH 2PtBu2)3 (P3P 3tBu, 3) are reported, along with the synthesis and characterization of ruthenium chloro complexes RuCl2(P 2P3tBu) (4), RuCl2(PhP 2P2tBu) (5), and RuCl2(P 3P3tBu) (6). The bulky P2P 3tBu (1) and P3P3tBu (3) ligands are the most sterically encumbered PP3-type ligands so far synthesized, and in all cases, only three phosphorus donors are able to bind to the metal center. Complexes RuCl2(PhP2P2 tBu) (5) and RuCl2(P3P3 tBu) (6) were characterized by crystallography. Low temperature solution and solid state 31P{1H} NMR were used to demonstrate that the structure of RuCl2(P2P 3tBu) (4) is probably analogous to that of RuCl 2(PhP2P2tBu) (5) which had been structurally characterized.