3-(Chloromethyl)-3-phenyl-1,2-dioxetane

Base Information

Chemical Name:3-(Chloromethyl)-3-phenyl-1,2-dioxetane
CAS No.:136749-73-0
Molecular Formula:C9H9ClO2
Molecular Weight:184.622
Hs Code.:
DSSTox Substance ID:DTXSID80576536
Nikkaji Number:J651.328J
Mol file:136749-73-0.mol

Synonyms:3-(Chloromethyl)-3-phenyl-1,2-dioxetane;136749-73-0;DTXSID80576536

Suppliers and Price of 3-(Chloromethyl)-3-phenyl-1,2-dioxetane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 3-(Chloromethyl)-3-phenyl-1,2-dioxetane

Chemical Property:

XLogP3:1.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:184.0291072
Heavy Atom Count:12
Complexity:157

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1C(OO1)(CCl)C2=CC=CC=C2

Technology Process of 3-(Chloromethyl)-3-phenyl-1,2-dioxetane

There total 2 articles about 3-(Chloromethyl)-3-phenyl-1,2-dioxetane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 136749-71-8
2-bromo-1-(chloromethyl)-1-phenylethyl hydroperoxide

: 136749-73-0
3-(chloromethyl)-3-phenyl-1,2-dioxetane

Guidance literature:: With sodium hydroxide; In dichloromethane; water; at 0 ℃; for 2.5h;

Reference yield:

: 3360-52-9
3-chloro-2-phenylprop-1-ene

: 136749-73-0
3-(chloromethyl)-3-phenyl-1,2-dioxetane

Guidance literature:: Multi-step reaction with 2 steps

1: 62 percent / 85percent H₂O₂, 1,3-dibromo-5,5-dimethylhydanthoin (DDH) / diethyl ether; H₂O / 2 h / 0 °C

2: 44 percent / NaOH / CH₂Cl₂; H₂O / 2.5 h / 0 °C

With sodium hydroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; dihydrogen peroxide; In diethyl ether; dichloromethane; water;