2-Nonanone, 1-cyclohexyl-1-(dimethylphenylsilyl)-

Base Information

• Chemical Name: 2-Nonanone, 1-cyclohexyl-1-(dimethylphenylsilyl)-
• CAS No.: 137466-58-1
• Molecular Formula: C₂₃H₃₈OSi
• Molecular Weight: 358.64
• Mol file: 137466-58-1.mol

Synonyms:

Chemical Property of 2-Nonanone, 1-cyclohexyl-1-(dimethylphenylsilyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-Nonanone, 1-cyclohexyl-1-(dimethylphenylsilyl)-

There total 1 articles about 2-Nonanone, 1-cyclohexyl-1-(dimethylphenylsilyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C15H23ClMgSi + n-octanoic acid chloride (111-64-8) → 1-Cyclohexyl-1-(dimethyl-phenyl-silanyl)-nonan-2-one (137466-58-1)

Guidance literature:

With copper(I) bromide dimethylsulfide complex; Multistep reaction; 1) THF, Et₂O, 45 min, -78 - 0 deg C, 2) 1.5 h, 25 deg C;

DOI:10.1021/jo00027a069

Reference yield:

1-Cyclohexyl-1-(dimethyl-phenyl-silanyl)-nonan-2-one (137466-58-1) → (E)-1-nonenylcyclohexane (114614-84-5)

Guidance literature:

With 18-crown-6 ether; potassium hydride; diisobutylaluminium hydride; Yield given. Multistep reaction; 1) THF, -78 deg C, 30 min, 2) 25 deg C, 12 h;

DOI:10.1021/jo00027a069

Reference yield:

1-Cyclohexyl-1-(dimethyl-phenyl-silanyl)-nonan-2-one (137466-58-1) → 1-cyclohexyl-1(Z)-nonene (127392-75-0)

Guidance literature:

With diisobutylaluminium hydride; toluene-4-sulfonic acid; Yield given. Multistep reaction; 1) THF, -78 deg C, 30 min, 2) 25 deg C, 12 h;

DOI:10.1021/jo00027a069

upstream raw materials:

n-octanoic acid chloride

Downstream raw materials:

1-cyclohexyl-1(Z)-nonene

(E)-1-nonenylcyclohexane