Hydrazine, 1-(4-iodophenyl)-2-phenyl-

Base Information

• Chemical Name: Hydrazine, 1-(4-iodophenyl)-2-phenyl-
• CAS No.: 137720-86-6
• Molecular Formula: C12H11IN2
• Molecular Weight: 310.137
• Mol file: 137720-86-6.mol

Synonyms:

Chemical Property of Hydrazine, 1-(4-iodophenyl)-2-phenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Hydrazine, 1-(4-iodophenyl)-2-phenyl-

There total 3 articles about Hydrazine, 1-(4-iodophenyl)-2-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

4-iodoazobenzene (6639-27-6) → 1-(4-iodophenyl)-2-phenylhydrazine (137720-86-6)

Guidance literature:

With tri-n-butyl-tin hydride; In benzene; Heating;

DOI:10.1021/jo00028a038

Reference yield: 68.0%

(E)-1-(4-iodophenyl)-2-phenyldiazene (21650-47-5) → 1-(4-iodophenyl)-2-phenylhydrazine (137720-86-6)

Guidance literature:

With C₃₀H₂₉BrMnNO₂P₂; hydrogen; potassium carbonate; In toluene; at 135 ℃; for 24h; under 60006 Torr; chemoselective reaction; Glovebox; Autoclave;

DOI:10.1021/acs.orglett.1c00659

Reference yield:

p-nitrobenzene iodide (636-98-6) → 1-(4-iodophenyl)-2-phenylhydrazine (137720-86-6)

Guidance literature:

Multi-step reaction with 3 steps

1: potassium carbonate; C₃₀H₂₉BrMnNO₂P₂; hydrogen / toluene / 24 h / 130 °C / 60006 Torr / Glovebox; Autoclave

2: acetic acid / ethanol / 48 h / 20 °C / Inert atmosphere

3: potassium carbonate; C₃₀H₂₉BrMnNO₂P₂; hydrogen / toluene / 24 h / 135 °C / 60006 Torr / Glovebox; Autoclave

With C₃₀H₂₉BrMnNO₂P₂; hydrogen; potassium carbonate; acetic acid; In ethanol; toluene;

DOI:10.1021/acs.orglett.1c00659

upstream raw materials:

4-iodoazobenzene

p-nitrobenzene iodide

(E)-1-(4-iodophenyl)-2-phenyldiazene

Downstream raw materials:

4-iodoazobenzene

(E)-1-(4-iodophenyl)-2-phenyldiazene