BENZOPHENONE-2,4'-DICARBOXYLIC ACID

Base Information

• Chemical Name: BENZOPHENONE-2,4'-DICARBOXYLIC ACID
• CAS No.: 85-58-5
• Molecular Formula: C15H10 O5
• Molecular Weight: 270.241
• Hs Code.: 2918300090
• Mol file: 85-58-5.mol

Synonyms:Benzoicacid, 2,4'-carbonyldi- (7CI,8CI); 2,4'-Dicarboxybenzophenone;2-(4-Carboxybenzoyl)benzoic acid; Benzophenone-2,4'-dicarboxylic acid; NSC 5003

Chemical Property of BENZOPHENONE-2,4'-DICARBOXYLIC ACID

Chemical Property:

• Melting Point: 241 °C
• Boiling Point: 556.6±35.0 °C(Predicted)
• PKA: 3.23±0.36(Predicted)
• Flash Point: 304.5oC
• PSA: 91.67000
• Density: 1.403±0.06 g/cm3(Predicted)
• LogP: 2.31400
• Solubility.: almost transparency in Methanol

Purity/Quality:

98%,99%, ^*data from raw suppliers

Benzophenone-2,4'-dicarboxylic Acid Monohydrate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BENZOPHENONE-2,4'-DICARBOXYLIC ACID

There total 10 articles about BENZOPHENONE-2,4'-DICARBOXYLIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(4-toluoyl)benzoic acid (85-55-2) → 2,4'-dicarboxybenzophenone (85-58-5)

Guidance literature:

With potassium permanganate;

Reference yield:

4-(p-tolyl)-1-tetralone (82101-39-1) → 2,4'-dicarboxybenzophenone (85-58-5)

Guidance literature:

With nitric acid; at 190 ℃;

Reference yield:

2-Chlor-3-(4-tolyl)-indenon-(1) (19772-67-9) → 2,4'-dicarboxybenzophenone (85-58-5)

Guidance literature:

With sodium hydroxide; potassium permanganate; In pyridine;

upstream raw materials:

(2-methylphenyl)(4-methylphenyl)methanone

2-(4-toluoyl)benzoic acid

4-(2-methylbenzoyl)benzoic acid

4-(p-tolyl)-1-tetralone

Downstream raw materials:

2,4'-carbonyl-di-benzoic acid dimethyl ester

2,4'-methanediyl-di-benzoic acid

anthraquinone-2-carboxylic acid

terephthalic acid

Refernces

Electrophilic Cleavage of Cyclopropanes. Acetolysis of Bicyclic and Tricyclic Cyclopropanes

10.1021/ja00290a042

The research investigates the acetolysis of a series of bicyclo[n.1.0]alkanes and [n.m.1]propellanes to understand the factors influencing the rates and products of these reactions. The study aims to determine the role of ring strain, ionization potentials, and bond polarization in the acetolysis process. Key chemicals used include various cyclopropane derivatives such as bicyclo[3.1.0]hexane, [3.2.1]propellane, and [4.2.1]propellane, with acetic acid serving as the solvent and p-toluenesulfonic acid as the catalyst. The researchers found that, contrary to expectations, strain energy relief has little correlation with reaction rates, while ionization potentials show a rough correlation. The degree of C-C bond polarization in the presence of a proton is a significant factor controlling the acetolysis rates. The study concludes that polarization of the central bond, influenced by the energy gap between occupied and unoccupied orbitals, is crucial for the reactivity of cyclopropanes. This finding highlights the importance of electronic factors over structural strain in determining reaction outcomes.

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 85-58-5 BENZOPHENONE-2,4'-DICARBOXYLIC ACID

Send

Send

Metric Ton KG G Pound L ML

Send

Send