Neodymium fluoride(ndf3)

Base Information

• Chemical Name: Neodymium fluoride(ndf3)
• CAS No.: 13709-42-7
• Molecular Formula: NdF3
• Molecular Weight: 201.235
• Hs Code.: 28469034
• Nikkaji Number: J96.256B
• Mol file: 13709-42-7.mol

Synonyms:NEODYMIUM FLUORIDE(NDF3);NEODYMIUMFLUORIDE;AKOS025294425;H10693

Chemical Property of Neodymium fluoride(ndf3)

Chemical Property:

• Appearance/Colour: Light grey powder
• Melting Point: 1410 °C
• Boiling Point: 19.5 °C at 760 mmHg
• PSA: 0.00000
• Density: 6.65
• LogP: 1.26060
• Sensitive.: Hygroscopic
• Solubility.: Soluble in aqueous solutions.
• Water Solubility.: insoluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 198.90294
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98%, ^*data from raw suppliers

Neodymium(III) fluoride, anhydrous 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn,Xi
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [F-].[F-].[F-].[Nd+3]
• Uses: Neodymium Fluoride is mainly used for glass, crystal and capacitors, and is the main raw material for making Neodymium Metal and alloys. Neodymium has a strong absorption band centered at 580 nm, which is very close to the human eye's maximum level of sensitivity making it useful in protective lenses for welding goggles. It is also used in CRT displays to enhance contrast between reds and greens. It is highly valued in glass manufacturing for its attractive purple coloring to glass. Neodymium trifluoride can be used extensively in the preparation and study of fluorinated glasses. Neodymium(III) fluoride, is used extensively in the preparation and study of fluorinated glasses.

Technology Process of Neodymium fluoride(ndf3)

There total 75 articles about Neodymium fluoride(ndf3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

NdCl3*NdF3 → neodymium(III) fluoride (13709-42-7) + neodymium trichloride (10024-93-8)

Guidance literature:

In neat (no solvent, solid phase); decompn. at 595°C;

DOI:10.1111/j.1151-2916.1996.tb09019.x

Reference yield:

ammonium fluoride + neodymium(III) oxide → neodymium(III) fluoride (13709-42-7)

Guidance literature:

In neat (no solvent); excess fluoride, 200°C, Pt-vessel; removal of excess fluoride on heating in a stream of dry inert gas to 450°C;;

Reference yield:

neodymium(III) oxide + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) → neodymium(III) fluoride (13709-42-7)

Guidance literature:

In neat (no solvent); byproducts: H2O; at elevated temp.;;

DOI:10.1021/ja02222a009 DOI:10.1007/BF01481992

upstream raw materials:

chlorine trifluoride

cadmium(II) fluoride

potassium tetrafluoridobromate(III)

BrF₃*SbF₅

Downstream raw materials:

hydrogen fluoride

zirconium(IV) fluoride

neodymium trichloride

neodymium(III) orthophosphate

Refernces

• 1、 Zmbov, K. F.,Margrave, J. L.. "". . p. 3167 - 3170. Retrieved 1966.
• 2、 Vieira Jr.,Ranieri,Tarelho,Wetter,Baldochi,Gomes,De Matos,De Rossi,Nogueira,Courrol,Barbosa,Maldonado,Morato. "Laser development of rare-earth doped crystals". . p. 231 - 239. Retrieved 2002.
• 3、 Zmbov, K. F.,Margrave, J. L.. "". . p. 3122 - 3125. Retrieved 1967.
• 4、 Lokshin,Tareeva. "Solubility of YF3, CeF3, PrF3, NdF 3, and DyF3 in solutions containing sulfuric and phosphoric acids". . p. 1830 - 1834. Retrieved 2007.
• 5、 Binnemans,Van Deun,Gorller-Walrand,Adam. "Optical properties of Nd3+-doped fluorophosphate glasses". . p. 455 - 460. Retrieved 1998.
• 6、 Sheft, I.,Martin, A. F.,Katz, J. J.. "". . p. 1557 - 1559. Retrieved 1956.
• 7、 Mai, Hao-Xin,Zhang, Ya-Wen,Si, Rui,Yan, Zheng-Guang,Sun, Ling-Dong,You, Li-Ping,Yan, Chun-Hua. "High-quality sodium rare-earth fluoride nanocrystals: Controlled synthesis and optical properties". . p. 6426 - 6436. Retrieved 2006.
• 8、 Maleev, Alexander A.,Fagin, Anatoly A.,Ilichev, Vasily A.,Lopatin, Mikhail A.,Konev, Alexey N.,Samsonov, Maksim A.,Fukin, Georgy K.,Bochkarev, Mikhail N.. "Lanthanide pentafluorophenolates. Synthesis, structure and luminescent properties". . p. 126 - 132. Retrieved 2013/11/19.
• 9、 Gong, Yu,Wang, Xuefeng,Andrews, Lester,Chen, Mingyang,Dixon, David A.. "Infrared spectra and quantum chemical calculations of the bridge-bonded HC(F)LnF2 (Ln = La-Lu) complexes". . p. 4443 - 4452. Retrieved 2011/10/10.