yomogin

Base Information

Chemical Name:yomogin
CAS No.:10067-18-2
Molecular Formula:C₁₅H₁₆O₃
Molecular Weight:244.29
Hs Code.:
Mol file:10067-18-2.mol

Synonyms:2-Naphthaleneaceticacid, 1,2b,3,4,4a,7-hexahydro-3a-hydroxy-4aa,8-dimethyl-a-methylene-7-oxo-, g-lactone (8CI);Naphtho[2,3-b]furan-2,6(3H,4H)-dione,3a,8a,9,9a-tetrahydro-5,8a-dimethyl-3-methylene-, [3aR-(3aa,8ab,9aa)]-; Yomogin (7CI); (-)-Yomogin

Suppliers and Price of yomogin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 7 raw suppliers

Chemical Property of yomogin

Chemical Property:

Vapor Pressure:4.61E-08mmHg at 25°C
Boiling Point:443.5°Cat760mmHg
Flash Point:199.7°C
PSA：43.37000
Density:1.2g/cm³
LogP:2.33970

Purity/Quality:: 98%,99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of yomogin

There total 22 articles about yomogin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

: 58964-72-0
3-oxo-11α-phenylseleno-7,8αH-eudesma-1,4-dien-12,8-olide

: 10067-18-2
yomogin

: 89293-17-4
(8aS,9aR)-3,5,8a-Trimethyl-9,9a-dihydro-4H,8aH-naphtho[2,3-b]furan-2,6-dione

Guidance literature:: With dihydrogen peroxide; In tetrahydrofuran; at 0 ℃; for 0.5h; Yields of byproduct given;
DOI:10.1248/cpb.31.3397

Reference yield: 33.0%

: 58964-72-0
3-oxo-11α-phenylseleno-7,8αH-eudesma-1,4-dien-12,8-olide

: 10067-18-2
yomogin

: 89293-17-4
(8aS,9aR)-3,5,8a-Trimethyl-9,9a-dihydro-4H,8aH-naphtho[2,3-b]furan-2,6-dione

Guidance literature:: With dihydrogen peroxide; acetic acid; In tetrahydrofuran; water;
DOI:10.1139/v87-108

Reference yield:

: 17974-84-4
(11S)-3-oxo-eudesma-1,4-dien-13-oic acid

: 10067-18-2
yomogin

Guidance literature:: Multi-step reaction with 9 steps

1: diethyl ether

2: 78 percent / p-TsOH / 72 h / Heating

3: 1,8-diazabicyclo<5.4.0>undec-7-ene / benzene / 1.5 h / 80 °C

4: 37 percent / CrO₃/tert-BuOH/Ac₂O / CCl₄ / 72 h / Heating

5: 1.) H₂; 2.) NaBH₄ / 1.) RhCl(PPh₃)3 / 1.) benzene/EtOH, 2-3 d; 2.) MeOH, -20 - -18 deg C, 30 min

6: 11.4 mg / 1.) 3 N NaOH; 2.) 3 N HCl / tetrahydrofuran / 1.) RT, 30 min; 2.) 1 h

7: 73 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone(DDQ) / dioxane / 27 h / Heating

8: 19 percent / 1.) lithium diisopropylamide (LDA); 2.) hexamethylphosphoramide (HMPA) / tetrahydrofuran / -78 °C / 1.) 30 min; 2.) 3 h

9: 37 percent / 35percent H₂O₂ / tetrahydrofuran / 0.5 h / 0 °C

With chromium(VI) oxide; hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydroxide; sodium tetrahydroborate; hydrogen; dihydrogen peroxide; acetic anhydride; toluene-4-sulfonic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; 2,3-dicyano-5,6-dichloro-p-benzoquinone; tert-butyl alcohol; lithium diisopropyl amide; RhCl(PPh₃)3; In tetrahydrofuran; 1,4-dioxane; tetrachloromethane; diethyl ether; benzene;
DOI:10.1248/cpb.31.3397