5H-Dibenzoborole, 5-phenyl-

Base Information

Chemical Name:5H-Dibenzoborole, 5-phenyl-
CAS No.:14010-93-6
Molecular Formula:C18H13B
Molecular Weight:240.112
Hs Code.:
DSSTox Substance ID:DTXSID50465483
Nikkaji Number:J1.880.235J
Wikidata:Q82291464
Mol file:14010-93-6.mol

Synonyms:5H-Dibenzoborole, 5-phenyl-;14010-93-6;DTXSID50465483

Suppliers and Price of 5H-Dibenzoborole, 5-phenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 5H-Dibenzoborole, 5-phenyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:240.1110306
Heavy Atom Count:19
Complexity:285

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(C2=CC=CC=C2C3=CC=CC=C31)C4=CC=CC=C4

Technology Process of 5H-Dibenzoborole, 5-phenyl-

There total 4 articles about 5H-Dibenzoborole, 5-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 873-51-8
phenylborondichloride

: 5565-85-5
5,5-dimethyl-5H-dibenzo[b,d]stannole

: 14010-93-6
5-phenyl-5H-dibenzo[d,b]borole

Guidance literature:: In toluene; byproducts: Me2SnCl2; (Ar); using Schlenk techniques; vac. transferring of toluene into flask with C12H8SnMe2 at -78°C; addn. dropwise via syringe of soln. of C6H5BCl2 at -78°C, slowly warming to room temp., stirring overnight; removal of solvent under vac., transferring to a sublimator, removal of Me2SnCl2 under static vac. at 40°C for 2 days, elem. anal.;
DOI:10.1021/om0209935

Reference yield:

: 13029-09-9
2,2'-dibromobiphenyl

: 14010-93-6
5-phenyl-5H-dibenzo[d,b]borole

Guidance literature:: Multi-step reaction with 2 steps

1: n-C₄H₉Li / diethyl ether

2: toluene

With n-C₄H₉Li; In diethyl ether; toluene;
DOI:10.1021/om0209935