2-Pentanol, 1-chloro-, (S)-

Base Information

Chemical Name:2-Pentanol, 1-chloro-, (S)-
CAS No.:141339-40-4
Molecular Formula:C5H11ClO
Molecular Weight:122.595
Hs Code.:
Mol file:141339-40-4.mol

Synonyms:

Suppliers and Price of 2-Pentanol, 1-chloro-, (S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-Pentanol, 1-chloro-, (S)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2-Pentanol, 1-chloro-, (S)-

There total 1 articles about 2-Pentanol, 1-chloro-, (S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 109-67-1
1-penten

: 139364-99-1
2-chloropentan-1-ol

: 107-87-9
2-Pentanone

: 141339-40-4
S-1-chloromethyl-1-butanol

: 141339-81-3
(R)-1-chloropentan-2-ol

Guidance literature:: With copper dichloride; [Pd(CH₃CN)2{(S)-BINAP}](BF₄)2; 1-phenylhexane-1,3,5-trione; In tetrahydrofuran; at 25 ℃; Further Variations:; Catalysts; Reagents; Product distribution;
DOI:10.1016/S0022-328X(00)00070-X

Reference yield:

: 141339-40-4
S-1-chloromethyl-1-butanol

: 123731-68-0
(S)-1,2-epoxypentane

Guidance literature:: With sodium hydroxide; In diethyl ether; at 20 ℃; for 22h;
DOI:10.1021/ja068901g

Reference yield:

: 141339-40-4
S-1-chloromethyl-1-butanol

: 929682-75-7
C₅₉H₈₆O₁₆Si₂

Guidance literature:: Multi-step reaction with 14 steps

1.1: NaOH / diethyl ether / 22 h / 20 °C

2.1: 1.91 g / CuCN / tetrahydrofuran / -78 - 0 °C

3.1: 1.36 g / molecular sieves 4 Angstroem; 2,6-di-tert-butylpyridine; AgOTf / CH₂Cl₂ / 14 h / 0 - 20 °C

4.1: MeOH / KOMe / 3 h

5.1: 1.46 g / TsOH*H₂O / acetone / 15 h / 20 °C

6.1: 77 percent / BF₃*Et₂O / CH₂Cl₂; pentane / 0.5 h / -20 °C

7.1: 84 percent / MeOH / KOMe / 4 h

8.1: 55 percent / DCC / DMAP / CH₂Cl₂

9.1: 96 percent / 2,6-lutidine / CH₂Cl₂ / 2 h

10.1: molecular sieves 4 Angstroem; NaBH₃CN; TMSCl / acetonitrile / 0 - 20 °C

10.2: 56.8 mg / DMAP / toluene; CH₂Cl₂ / 3 h

11.1: DDQ; water / CH₂Cl₂ / 16 h / 20 °C

12.1: 2,4,6-trichlorobenzoyl chloride; Et₃N / toluene / 1.5 h / 20 °C

12.2: 54.6 mg / DMAP / toluene / 2 h

13.1: RuCl₂(IMes)(PCy₃)=CHPh / CH₂Cl₂ / 4 h / Heating

14.1: 60 mg / H₂ / RhCl(PPh₃)3 / ethanol / 760 Torr

With 2,6-dimethylpyridine; methanol; sodium hydroxide; chloro-trimethyl-silane; 2,6-di-tert-butyl-pyridine; 4 A molecular sieve; 2,4,6-trichlorobenzoyl chloride; water; hydrogen; silver trifluoromethanesulfonate; sodium cyanoborohydride; toluene-4-sulfonic acid; triethylamine; dicyclohexyl-carbodiimide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; dmap; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene](benzylidene)Ru(II) dichloride; RhCl(PPh₃)3; boron trifluoride diethyl etherate; potassium methanolate; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; acetone; toluene; acetonitrile; pentane;
DOI:10.1021/ja068901g