Hexylmethyldichlorosilane

Base Information

• Chemical Name: Hexylmethyldichlorosilane
• CAS No.: 14799-94-1
• Molecular Formula: C7H16Cl2Si
• Molecular Weight: 199.196
• Hs Code.: 2931900090
• UNII: 798Y7DR4MN
• DSSTox Substance ID: DTXSID90884770
• Nikkaji Number: J227.192C
• Wikidata: Q82863412
• Mol file: 14799-94-1.mol

Synonyms:Hexylmethyldichlorosilane;14799-94-1;Dichlorohexylmethylsilane;Dichloro-hexyl-methylsilane;n-Hexylmethyldichlorosilane;Silane, dichlorohexylmethyl-;dichloro(hexyl)(methyl)silane;2,2-dichloro-2-silaoctane;798Y7DR4MN;C7H16Cl2Si;EINECS 238-864-8;Dichloro(hexyl)methylsilane;UNII-798Y7DR4MN;N-HEXYLDICHLOROMETHYLSILANE;DTXSID90884770;88002-83-9;methylhexyldichlorosilane;C7-H16-Cl2-Si;Dichloro(hexyl)methylsilane #;SCHEMBL523164;KKRMHVJQWMXYBZ-UHFFFAOYSA-;DTXCID001024194;MFCD00039295;AKOS006230007;CS-0198939;FT-0637138;H0855;D90963

Chemical Property of Hexylmethyldichlorosilane

Chemical Property:

• Vapor Pressure: 0.732mmHg at 25°C
• Melting Point: <0°C
• Refractive Index: n20/D 1.439
• Boiling Point: 191 °C at 760 mmHg
• Flash Point: 64 °C
• PSA: 0.00000
• Density: 0.983 g/cm³
• LogP: 4.11630
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 198.0398324
• Heavy Atom Count: 10
• Complexity: 83.7

Purity/Quality:

98% ^*data from raw suppliers

Dichlorohexylmethylsilane min. 95.0 % ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCC[Si](C)(Cl)Cl

Technology Process of Hexylmethyldichlorosilane

There total 14 articles about Hexylmethyldichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Dichloromethylsilane (75-54-7) + 1-hexene (592-41-6,25067-06-5) → n-hexylmethyldichlorosilane (14799-94-1)

Guidance literature:

at 90 ℃; for 5h; Inert atmosphere;

Reference yield: 95.2%

Dichloromethylsilane (75-54-7) + cis-2-hexene (7688-21-3) → n-hexylmethyldichlorosilane (14799-94-1)

Guidance literature:

cis-2-hexene; With diethylenetriaminepentaacetic acid (DTPA)-functionalized silica supported Pt; at 60 ℃; for 0.5h;

Dichloromethylsilane; at 60 ℃; for 4h; Reagent/catalyst;

DOI:10.1039/c8ra01828f

Reference yield: 16.0%

Dichloromethylsilane (75-54-7) + 1-Chlorohexane (544-10-5) + hexyltrichlorosilane (928-65-4) → n-hexylmethyldichlorosilane (14799-94-1)

Guidance literature:

tributylphosphine;

upstream raw materials:

Dichloromethylsilane

1-hexene

propene

ethene

Downstream raw materials:

1-hexene

1-penten

Dichloromethylvinylsilane

dimethylsilicon dichloride

Refernces

• 1、 Li, Laiming,Li, Youxin,Yan, Jincong,Cao, Hang,Shao, Dongyun,Bao, James J.. "A magnetically recyclable superparamagnetic silica supported Pt nanocatalyst through a multi-carboxyl linker: Synthesis, characterization, and applications in alkene hydrosilylation". . p. 12696 - 12709. Retrieved 2019.
• 2、 Simon, Cdric,Amatore, Muriel,Aubert, Corinne,Petit, Marc. "Mild niobium-catalyzed [2 + 2 + 2] cycloaddition of sila-triynes: Easy access to polysubstituted benzosilacyclobutenes". . p. 844 - 847. Retrieved 2015.
• 3、 Li, Laiming,Li, Youxin,Assefa, Aschenaki,Bao, James J.. "Preparation, characterization and evaluation of a series of heterogeneous platinum catalysts immobilized on magnetic silica with different acid ligands". . p. 779 - 787. Retrieved 2019/08/12.