4-morpholinedithiocarbamate

Base Information

• Chemical Name: 4-morpholinedithiocarbamate
• CAS No.: 3581-30-4
• Molecular Formula: C5H9 N O S2
• Molecular Weight: 163.265
• Hs Code.: 2934999090
• Mol file: 3581-30-4.mol

Synonyms:(Oxydiethylene)dithiocarbamicacid; 4-Morpholinecarboxylic acid, dithio-; Morpholine-N-carbodithioic acid;Morpholinedithiocarboxylic acid; Morpholinodithiocarboxylic acid;N-Morpholinedithiocarboxylic acid

Chemical Property of 4-morpholinedithiocarbamate

Chemical Property:

• Boiling Point: 239°Cat760mmHg
• Flash Point: 98.4°C
• PSA: 83.36000
• Density: g/cm³
• LogP: 0.47120

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-morpholinedithiocarbamate

There total 7 articles about 4-morpholinedithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

morpholine (110-91-8,99108-56-2) + carbon disulfide (75-15-0,12122-00-8) → morpholine-4-carbodithioic acid (3581-30-4)

Guidance literature:

In chloroform; for 1h;

Reference yield:

morpholine (110-91-8,99108-56-2) → morpholine-4-carbodithioic acid (3581-30-4)

Guidance literature:

With water;

DOI:10.1039/jr9500000642

Reference yield:

→ morpholine-4-carbodithioic acid (3581-30-4)

Guidance literature:

With sulfur; at 220 ℃; bzw. 150grad;

DOI:10.1021/ja01192a050

upstream raw materials:

morpholine

formaldehyd

4-(morpholinomethyl)morpholine

carbon disulfide

Downstream raw materials:

N-(2,6-dimethyl-phenyl)-formimidic morpholine-4-carbothioic thioanhydride

benzoic morpholine-4-carbothioic thioanhydride

chloro-diphenyl-acetic morpholine-4-carbothioic thioanhydride

Morpholine-4-carbodithioic acid (E)-3-furan-2-yl-3-oxo-1-phenyl-propenyl ester

Refernces

• 1、 Mukherjee, Titas,Sen, Buddhadeb,Patra, Animesh,Banerjee, Snehasis,Hundal, Geeta,Chattopadhyay, Pabitra. "Cyclometalated rhodium(III) complexes bearing dithiocarbamate derivative: Synthesis, characterization, interaction with DNA and biological study". . p. 127 - 134. Retrieved 2014.
• 2、 Vishwakarma, Ramesh Kumar,Kumar, Saurabh,Singh, Krishna Nand. "Visible-Light-Induced Photocatalytic Synthesis of β-Keto Dithiocarbamates via Difunctionalization of Styrenes". supporting information. p. 4147 - 4151. Retrieved 2021/05/26.
• 3、 Spillier, Quentin,Ravez, Séverine,Unterlass, Judith,Corbet, Cyril,Degavre, Charline,Feron, Olivier,Frédérick, Rapha?l. "Structure–activity relationships (SARs) of α- ketothioamides as inhibitors of phosphoglycerate dehydrogenase (PHGDH)". . . Retrieved 2020/02/11.