Hydroperoxide, 3-phenyl-2-propenyl, (E)-

Base Information

• Chemical Name: Hydroperoxide, 3-phenyl-2-propenyl, (E)-
• CAS No.: 141524-11-0
• Molecular Formula: C₉H₁₀O₂
• Molecular Weight: 150.177
• Mol file: 141524-11-0.mol

Synonyms:

Chemical Property of Hydroperoxide, 3-phenyl-2-propenyl, (E)-

Chemical Property:

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Hydroperoxide, 3-phenyl-2-propenyl, (E)-

There total 2 articles about Hydroperoxide, 3-phenyl-2-propenyl, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

cinnamyl chloride (2687-12-9) → 1-phenylprop-2-enyl hydroxyperoxide (65127-27-7) + 3-phenylprop-2-enyl hydroxyperoxide (141524-11-0)

Guidance literature:

With silver tetrafluoroborate; dihydrogen peroxide; In diethyl ether; Yields of byproduct given;

DOI:10.1039/C39920000428

Reference yield:

tert-butyl 4-phenylperbutenoate (59710-69-9) → 1-phenylprop-2-enyl hydroxyperoxide (65127-27-7) + 3-phenylprop-2-enyl hydroxyperoxide (141524-11-0)

Guidance literature:

tert-butyl 4-phenylperbutenoate; With 3-HYDROXYPYRIDINE; In benzene; at 25 ℃; for 0.5h; UV-irradiation;

With triphenylphosphine; In benzene; Reagent/catalyst; Solvent; Kinetics;

DOI:10.1021/jo801501e

Reference yield:

mercury(II) diacetate (1600-27-7) + 3-phenylprop-2-enyl hydroxyperoxide (141524-11-0) → (BrHg)(C6H5)C3H4O2 (141524-13-2)

Guidance literature:

With potassium bromide; treatment of aldehyde (acetaldehyde or iPrCHO or EtCH(Me)CHO or CCl3CHO) and hydroperoxide with CF3CO2H, then treatment with Hg(OAc)2 and HClO4, then anion exchange with KBr; detn. by (1)H, (13)C NMR and elem. anal.;

DOI:10.1039/C39920000428

upstream raw materials:

cinnamyl chloride

tert-butyl 4-phenylperbutenoate

Downstream raw materials:

(BrHg)(C₆H₅)C₃H₄O₂

Refernces

• 1、 Nara, Susheel J.,Jha, Mukund,Brinkhorst, Johan,Zemanek, Tony J.,Pratt, Derek A.. "A simple Cu-catalyzed coupling approach to substituted 3-pyridinol and 5-pyrimidinol antioxidants". supporting information; experimental part. p. 9326 - 9333. Retrieved 2009/04/06.