Mercuric acetate

Base Information

• Chemical Name: Mercuric acetate
• CAS No.: 1600-27-7
• Deprecated CAS: 148333-06-6,19701-15-6,6129-23-3,7619-62-7,6129-23-3,7619-62-7
• Molecular Formula: C2H4O2.1/2Hg
• Molecular Weight: 318.679
• Hs Code.: 28521000
• European Community (EC) Number: 216-491-1,209-766-2
• ICSC Number: 0978
• UN Number: 1629
• UNII: R0G1MCT8Y5
• DSSTox Substance ID: DTXSID4042123
• Nikkaji Number: J3.371E
• Wikipedia: Mercury(II) acetate,Mercury(II)_acetate
• Mol file: 1600-27-7.mol

Synonyms:mercuric acetate;mercuric acetate, (197)mercury-labeled;mercuric acetate, (203)mercury-labeled

Chemical Property of Mercuric acetate

Chemical Property:

• Appearance/Colour: white or off-white powder
• Vapor Pressure: 13.9mmHg at 25°C
• Melting Point: 179-182 °C(lit.)
• Boiling Point: 117.1 °C at 760 mmHg
• Flash Point: 40 °C
• PSA: 80.26000
• Density: 3.29 g/cm³
• LogP: -2.49010
• Storage Temp.: Store at RT.
• Sensitive.: Light Sensitive
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 319.997252
• Heavy Atom Count: 9
• Complexity: 25.5
• Transport DOT Label: Poison

Purity/Quality:

Mercury(II) acetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T+, N
• Hazard Codes: T+,N
• Statements: 26/27/28-33-50/53
• Safety Statements: 13-28-36-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Mercury Compounds, Inorganic
• Canonical SMILES: CC(=O)[O-].CC(=O)[O-].[Hg+2]
• Inhalation Risk: A harmful concentration of airborne particles can be reached quickly when dispersed.
• Effects of Short Term Exposure: The substance is irritating to the eyes, skin and respiratory tract. The substance may cause effects on the kidneys. Medical observation is indicated.
• Effects of Long Term Exposure: Repeated or prolonged contact may cause skin sensitization. The substance may have effects on the central nervous system, peripheral nervous system and kidneys. This may result in ataxia, sensory and memory disturbances, tremors, muscle weakness and kidney impairment. The substance may have effects on male fertility. May cause heritable genetic damage to human germ cells.
• Description: Mercury (II) acetate is the chemical compound with the formula Hg(O2CCH3)2. Commonly abbreviated Hg (OAc)2, this compound is employed as a reagent to generate organomercury compounds from unsaturated organic precursors.
• Physical properties: Mercury(II) acetate is a crystalline solid consisting of isolated Hg(OAc)2 molecules with Hg-O distances of 2.07 ?. Three long, weak intermolecular Hg···O bonds of about 2.75 ? are also present,resulting in a slightly distorted square pyramidal coordination geometry at Hg.
• Uses: Mercuric acetate is used as an oxidizing agent in organic synthesis. It is used in oxymercuration of double bonds. Mercuric acetate is used in non-aqueous titration. It is employed in the manufacture of phenyl mercury compounds which have pharmaceutical applications. It removes the acetamidomethyl protecting group from protected thiol, and converts thiocarbonate esters into dithiocarbonates. It promotes the addition of hydroxide and alkoxide across carbon-carbon double bonds. Used in determination of nitrate in chromium compounds Chiefly for mercuration of organic compounds; for the absorption of ethylene.

Technology Process of Mercuric acetate

There total 34 articles about Mercuric acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

mercury(II) diacetate (1600-27-7) → thiobasic mercury(II) acetate (592-63-2,631-60-7,1600-27-7,33525-50-7,54379-42-9,73206-35-6)

Guidance literature:

With hydrogen sulfide; In water; from concd. Hg(CH3CO2)2 solution;

Reference yield:

mercury(II) diacetate (1600-27-7) + mercury sulfide → thiobasic mercury(II) acetate (592-63-2,631-60-7,1600-27-7,33525-50-7,54379-42-9,73206-35-6)

Guidance literature:

in concd. warm Hg(CH3CO2)2 soln.;

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + mercury(II) diacetate (1600-27-7) → thiobasic mercury(II) acetate (592-63-2,631-60-7,1600-27-7,33525-50-7,54379-42-9,73206-35-6)

Guidance literature:

In water; in cold satd. aq. Hg(CH3CO2)2 soln. in light or without light;

upstream raw materials:

acetic acid

acetic anhydride

mercury(II) oxide

mercuric carbonate

Downstream raw materials:

2-bromopyridine-N-oxide

2,6-dibromopyridin N-oxide

β-ethoxy-phenethylmercury (1+); chloride

β-ethoxy-phenethylmercury (1+); bromide

Refernces

• 1、 Roll, Joachim,Werner, Helmut. "". . p. 93 - 98. Retrieved 1988.
• 2、 -. "Porphyrin compound, process for producing porphyrin compound, three-dimensional optical recording material, and three-dimensional optical recording medium". Page/Page column 25. . Retrieved 2010/11/28.
• 3、 Aboulkacem, Said,Tyrra, Wieland,Pantenburg, Ingo. "Syntheses, characterizations, and crystal structures of β-diketiminato compounds of pentafluorophenyl group 12 derivatives, HC{[C(Me)N(C6H3-2,6-i-Pr2)]2}MC 6F5 (M = Zn, Cd)". . p. 1569 - 1574. Retrieved 2008/10/08.