Stanate

Base Information

• Chemical Name: Stanate
• CAS No.: 106344-20-1
• Deprecated CAS: 110946-74-2
• Molecular Formula: C₃₄H₃₆Cl₂N₄O₄Sn
• Molecular Weight: 754.3
• UNII: 0KAE1U0G7Q
• Metabolomics Workbench ID: 149332
• NCI Thesaurus Code: C152424
• Mol file: 106344-20-1.mol

Synonyms:Sn mesoporphyrin;SNMPP;stanate;stannsoporfin;tin mesoporphyrin

Chemical Property of Stanate

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 1096.1°Cat760mmHg
• Flash Point: 616.7°C
• PSA: 130.76000
• Density: g/cm³
• LogP: 1.88710
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 8
• Exact Mass: 754.113564
• Heavy Atom Count: 45
• Complexity: 949

Purity/Quality:

97% ^*data from raw suppliers

Sn(IV)MesoporphyrinIXDichloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC1=C(C2=NC1=CC3=C(C(=C([N-]3)C=C4C(=C(C(=CC5=NC(=C2)C(=C5C)CC)[N-]4)C)CCC(=O)O)CCC(=O)O)C)C.[Cl-].[Cl-].[Sn+4]
• Recent ClinicalTrials: Follow up Study of Patients Having Participated in Clinical Trial 64,185-204
• Recent EU Clinical Trials: A 5-Year, Extension, Follow-up, Blinded-Outcomes Trial of Subjects Having Received Stannsoporfin or Placebo in Clinical Trial 64,185-202
• Uses: Control of hyperbilirubinemia in preterm and term newborns (inhibitor of bilirubin). Sn(IV) Mesoporphyrin IX Dichloride is a potent competitive inhibitors of heme oxygenase. It is a useful compound to study tumor angiogenesis in human pancreatic cancer.

Technology Process of Stanate

There total 4 articles about Stanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.2%

tin protoporphyrin IX dicholoride (14325-05-4) → tin mesoporphyrin (106344-20-1,830320-88-2)

Guidance literature:

With Darko-KBG; In 1-methyl-pyrrolidin-2-one; at 50 ℃; for 1h; under 3102.97 Torr; Product distribution / selectivity;

Reference yield:

mesoprotoporphyrin IX dihydrochloride (68938-72-7) → tin mesoporphyrin (106344-20-1,830320-88-2)

Guidance literature:

mesoprotoporphyrin IX dihydrochloride; With formic acid; stannous octoate; acetic acid; for 24h;

With hydrogenchloride; water;

Reference yield:

mesoprotoporphyrin IX dihydrochloride (68938-72-7) + tin(II) oxide → tin mesoporphyrin (106344-20-1,830320-88-2)

Guidance literature:

tin(II) oxide; In acetic acid; at 20 - 65 ℃; Inert atmosphere;

mesoprotoporphyrin IX dihydrochloride; In formic acid; acetic acid; at 60 - 65 ℃; for 18h; Inert atmosphere;

With hydrogenchloride; water; at 20 - 95 ℃; Product distribution / selectivity; Inert atmosphere;

upstream raw materials:

mesoprotoporphyrin IX dihydrochloride

tin protoporphyrin IX dicholoride

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