4-FLUORO-4'-IODOBENZOPHENONE

Base Information

• Chemical Name: 4-FLUORO-4'-IODOBENZOPHENONE
• CAS No.: 141763-55-5
• Molecular Formula: C13H8FIO
• Molecular Weight: 326.109
• Hs Code.: 2914700090
• Mol file: 141763-55-5.mol

Synonyms:Methanone,(4-fluorophenyl)(4-iodophenyl);4-FLUORO-4'-IODOBENZOPHENONE;4-iodo-4'-fluorobenzophenone;

Chemical Property of 4-FLUORO-4'-IODOBENZOPHENONE

Chemical Property:

• Vapor Pressure: 9.23E-06mmHg at 25°C
• Boiling Point: 373oC at 760 mmHg
• Flash Point: 179.4oC
• PSA: 17.07000
• Density: 1.682g/cm3
• LogP: 3.66130

Purity/Quality:

98%min ^*data from raw suppliers

4-Fluoro-4'-iodobenzophenone 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-FLUORO-4'-IODOBENZOPHENONE

There total 2 articles about 4-FLUORO-4'-IODOBENZOPHENONE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

fluorobenzene (462-06-6) + 4-iodobenzoic acid chloride (1711-02-0) → 4-fluoro-4'-iodobenzophenone (141763-55-5)

Guidance literature:

With aluminum (III) chloride; at 40 - 50 ℃;

Reference yield:

4-fluoro-4'-iododiphenylmethanol (141763-56-6) + difluoro-(4-fluoro-4'-iododiphenyl)methane (142687-15-8) → 4-fluoro-4'-iodobenzophenone (141763-55-5)

Guidance literature:

With pyridinium chlorochromate; In diethyl ether; dichloromethane;

Reference yield: 78.0%

acetylene (74-86-2,25067-58-7) + 4-fluoro-4'-iodobenzophenone (141763-55-5) → 4,4'-bis(4-fluorobenzoyl)diphenylacetylene

Guidance literature:

With copper(l) iodide; diethylamine; palladium; at 18 - 20 ℃; for 10h;

DOI:10.1023/B:RUGC.0000007621.86396.78

upstream raw materials:

4-fluoro-4'-iododiphenylmethanol

difluoro-(4-fluoro-4'-iododiphenyl)methane

fluorobenzene

4-iodobenzoic acid chloride

Downstream raw materials:

C₃₀H₁₆F₁₀O₂

Refernces

• 1、 -. "SULPHUR-CONTAINING TRIAZINE MONOMER THAT CAN BE USED FOR THE SYNTHESIS OF A POLYMER MEMBRANE FOR A FUEL CELL". Paragraph 0146; 0147; 0148; 0149; 0150; 0151; 0152. . Retrieved 2013/07/25.
• 2、 Maeyama, Katsuya,Tsukamoto, Tadashi,Suzuki, Masanori,Higashibayashi, Shuhei,Sakurai, Hidehiro. "Synthesis of aromatic polyketones bearing 1,1'-binaphthyl-2,2'-dioxy units through Suzuki-Miyaura coupling polymerization". supporting information. p. 1445 - 1446. Retrieved 2013/05/08.