Sulfonium, [(4-methoxyphenyl)methyl]dimethyl-, chloride

Base Information

• Chemical Name: Sulfonium, [(4-methoxyphenyl)methyl]dimethyl-, chloride
• CAS No.: 14181-51-2
• Molecular Formula: C10H15OS.Cl
• Molecular Weight: 218.748
• Mol file: 14181-51-2.mol

Synonyms:

Chemical Property of Sulfonium, [(4-methoxyphenyl)methyl]dimethyl-, chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Sulfonium, [(4-methoxyphenyl)methyl]dimethyl-, chloride

There total 1 articles about Sulfonium, [(4-methoxyphenyl)methyl]dimethyl-, chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dimethylsulfide (75-18-3) + p-methoxybenzyl chloride (824-94-2) → (4-methoxybenzyl)dimethylsulphonium chloride (14181-51-2)

Guidance literature:

DOI:10.1039/jr9600004747

Reference yield: 92.0%

(4-methoxybenzyl)dimethylsulphonium chloride (14181-51-2) + 3-(3,4,5-trimethoxy-phenyl)-benzofuran-4-carbaldehyde → 4-[(2S,3S)-3-(4-Methoxy-phenyl)-oxiranyl]-3-(3,4,5-trimethoxy-phenyl)-benzofuran

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; at 25 ℃;

DOI:10.1021/ol027574o

Reference yield:

(4-methoxybenzyl)dimethylsulphonium chloride (14181-51-2) → dimethylsulfide (75-18-3) + 4-Methoxybenzyl alcohol (105-13-5)

Guidance literature:

In water; at 80 ℃; Rate constant; Mechanism; Thermodynamic data; other solvent, also in presence of NaCl or NaClO4, determination of solvent deuterium isotope effect and secondary deuterium isotope effect; ΔH(excit.), ΔS(excit.), ΔG(excit), ΔG_{80 deg C};

DOI:10.1021/jo00098a033

upstream raw materials:

dimethylsulfide

p-methoxybenzyl chloride

Downstream raw materials:

1-(isothiocyanatomethyl)-4-methoxybenzene

p-methoxybenzyl thiocyanate

dimethylsulfide

4-Methoxybenzyl alcohol