Technology Process of Cobalt, nonacarbonyl-m3-methylidynetri-, triangulo
There total 5 articles about Cobalt, nonacarbonyl-m3-methylidynetri-, triangulo which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
carbon monoxide; triethylamine;
In
benzene;
through stirred soln. of Co complex, phenolderiv. and excess of Et3N was bubbled CO for 6 h at room temp.; react. mixt. was poured into 10% aq. HCl, sepd. organic layer was dried(MgSO4 or Na2SO4) and concd. in vac.; chromy. (silicic acid), hexane elution gave HCCo3(CO)9, identified by IR; CH2Cl2 eluted desired product, recrystn. from hexane; elem. anal.;
DOI:10.1016/S0022-328X(00)93764-1
- Guidance literature:
-
With
carbon monoxide; triethylamine;
In
benzene;
through stirred soln. of Co complex, phenolderiv. and excess of Et3N was bubbled CO for 6 h at room temp.; react. mixt. was poured into 10% aq. HCl, sepd. organic layer was dried(MgSO4 or Na2SO4) and concd. in vac.; chromy. (silicic acid), hexane elution gave HCCo3(CO)9, identified by IR; CH2Cl2 eluted desired product, recrystn. from hexane; elem. anal.;
DOI:10.1016/S0022-328X(00)93764-1
- Guidance literature:
-
With
triethylamine;
In
benzene;
(CO); mixt. of thiolate, Co complex and Et3N was stirred for 10 h at room temp; mixt. was poured into water, org. layer was washed, dried and evapd. invac., residue was chromd. (SiO2*aq.); hexane elution yielded HCCo3(CO)9(IR); elution with benzene gave Co3(CO)4(SPh)5, identified by IR;
DOI:10.1016/S0022-328X(00)90538-2
